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The molar volume of gases around STP and at atmospheric pressure can be calculated with an accuracy that is usually sufficient by using the ideal gas law. The molar volume of any ideal gas may be calculated at various standard reference conditions as shown below: V m = 8.3145 × 273.15 / 101.325 = 22.414 dm 3 /mol at 0 °C and 101.325 kPa
Until 1982, STP was defined as a temperature of 273.15 K (0 °C, 32 °F) and an absolute pressure of 101.325 kPa (1 atm). Since 1982, STP is defined as a temperature of 273.15 K (0 °C, 32 °F) and an absolute pressure of 100 kPa (1 bar). Conversions between each volume flow metric are calculated using the following formulas: Prior to 1982,
An actual volume can be converted to a standard volume using the following equation: [6] [7] V s = V a × F p × F t × (F pv) 2. Where, V s: standard volume V a: actual volume (sometimes shown as V r for registered volume) F p: pressure factor (sometimes shown as P m for pressure multiplier)
When positive pressure is applied to a standard cubic foot of gas, it is compressed. When a vacuum is applied to a standard cubic foot of gas, it expands. The volume of gas after it is pressurized or rarefied is referred to as its "actual" volume. SCF and ACF for an ideal gas are related in accordance with the combined gas law: [2] [3]
Isotherms of an ideal gas for different temperatures. The curved lines are rectangular hyperbolae of the form y = a/x. They represent the relationship between pressure (on the vertical axis) and volume (on the horizontal axis) for an ideal gas at different temperatures: lines that are farther away from the origin (that is, lines that are nearer to the top right-hand corner of the diagram ...
R is the gas constant, which must be expressed in units consistent with those chosen for pressure, volume and temperature. For example, in SI units R = 8.3145 J⋅K −1 ⋅mol −1 when pressure is expressed in pascals, volume in cubic meters, and absolute temperature in kelvin. The ideal gas law is an extension of experimentally discovered ...
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Note that the m³ gas conversion factor takes into account a difference in the standard temperature base for measurement of gas volumes in metric and imperial units. The standard temperature for metric measurement is 15 degrees Celsius (i.e. 59 degrees Fahrenheit) while for English measurement the standard temperature is 60 °F.