Search results
Results from the WOW.Com Content Network
The Cope reaction or Cope elimination, developed by Arthur C. Cope, is the elimination reaction of an N-oxide to an alkene and a hydroxylamine. [1] [2] [3] [4]
The Cope rearrangement is an extensively studied organic reaction involving the [3,3] ... giving only elimination products at 200 °C.
The Cope elimination (Cope reaction) is the elimination of a tertiary amine oxide to yield an alkene and a hydroxylamine through an E i mechanism. [13] [21] The Cope elimination was used in the synthesis of a mannopyranosylamine mimic. [22]
Arthur C. Cope (June 27, 1909 – June 4, 1966) was an American organic chemist and member of the United States National Academy of Sciences. He is credited with the development of several important chemical reactions which bear his name including the Cope elimination and the Cope rearrangement. Cope was born on June 27, 1909, in Dunreith, Indiana.
The Cope elimination is very similar to the Hofmann elimination in principle but occurs under milder conditions. It also favors the formation of the Hofmann product, and for the same reasons. It also favors the formation of the Hofmann product, and for the same reasons.
Pyrolytic elimination. Amine oxides, when heated to 150–200 °C undergo a Cope reaction to form a hydroxylamine and an alkene. The reaction requires the alkyl groups to have hydrogens at the beta-carbon (i.e. works with ethyl and above, but not methyl) Reduction to amines.
President-elect Donald Trump listens to Elon Musk as he arrives to watch SpaceX's mega rocket Starship lift off for a test flight from Starbase in Boca Chica, Texas, Tuesday, Nov. 19, 2024.
Pages in category "Elimination reactions" The following 21 pages are in this category, out of 21 total. ... Chugaev elimination; Cope reaction; Corey–Winter olefin ...