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A quantum number beginning in n = 3,ℓ = 0, describes an electron in the s orbital of the third electron shell of an atom. In chemistry, this quantum number is very important, since it specifies the shape of an atomic orbital and strongly influences chemical bonds and bond angles. The azimuthal quantum number can also denote the number of ...
For example, the "4s subshell" is a subshell of the fourth (N) shell, with the type (s) described in the first row. The second column is the azimuthal quantum number (ℓ) of the subshell. The precise definition involves quantum mechanics, but it is a number that characterizes the subshell.
For a given value of the principal quantum number n, the possible values of ℓ range from 0 to n − 1; therefore, the n = 1 shell only possesses an s subshell and can only take 2 electrons, the n = 2 shell possesses an s and a p subshell and can take 8 electrons overall, the n = 3 shell possesses s, p, and d subshells and has a maximum of 18 ...
The maximum number of electrons in a subshell is equal to 2(2 l + 1), where the azimuthal quantum number l is equal to 0, 1, 2, and 3 for s, p, d, and f subshells, so that the maximum numbers of electrons are 2, 6, 10, and 14 respectively.
For example, the 3d subshell has n = 3 and l = 2. The maximum number of electrons that can be placed in a subshell is given by 2(2 l + 1). This gives two electrons in an s subshell, six electrons in a p subshell, ten electrons in a d subshell and fourteen electrons in an f subshell.
The spin magnetic quantum number m s specifies the z-axis component of the spin angular momentum for a particle having spin quantum number s. For an electron, s is 1 ⁄ 2 , and m s is either + 1 ⁄ 2 or − 1 ⁄ 2 , often called "spin-up" and "spin-down", or α and β.
Second quantization, also referred to as occupation number representation, is a formalism used to describe and analyze quantum many-body systems. In quantum field theory, it is known as canonical quantization, in which the fields (typically as the wave functions of matter) are thought of as field operators, in a manner similar to how the physical quantities (position, momentum, etc.) are ...
During the period between 1916 and 1925, much progress was being made concerning the arrangement of electrons in the periodic table.In order to explain the Zeeman effect in the Bohr atom, Sommerfeld proposed that electrons would be based on three 'quantum numbers', n, k, and m, that described the size of the orbit, the shape of the orbit, and the direction in which the orbit was pointing. [10]