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Selenium tetrafluoride (Se F 4) is an inorganic compound.It is a colourless liquid that reacts readily with water. It can be used as a fluorinating reagent in organic syntheses (fluorination of alcohols, carboxylic acids or carbonyl compounds) and has advantages over sulfur tetrafluoride in that milder conditions can be employed and it is a liquid rather than a gas.
Selenium tetrafluoride is a laboratory-scale fluorinating agent. The only stable chlorides are selenium tetrachloride (SeCl 4) and selenium monochloride (Se 2 Cl 2), which might be better known as selenium(I) chloride and is structurally analogous to disulfur dichloride.
Pentafluoroselenium hypofluorite can be produced from the reaction of selenium dioxide or selenium oxychloride with fluorine gas in the presence of silver difluoride catalyst. However, the reaction yield is low (14% [ 3 ] ), and it is hard to purify due to large amount of SeF 6 byproduct.
Selenium forms two oxides: selenium dioxide (SeO 2) and selenium trioxide (SeO 3). Selenium dioxide is formed by the reaction of elemental selenium with oxygen: [5] + It is a polymeric solid that forms monomeric SeO 2 molecules in the gas phase. It dissolves in water to form selenous acid, H 2 SeO 3.
Despite the low reactivity of the tetrafluoroborate anion in general, BF − 4 serves as a fluorine source to deliver an equivalent of fluoride. [2] The Balz–Schiemann reaction for the synthesis of aryl fluorides is the best known example of such a reaction. [3]
Seleninyl fluoride can be produced by the reaction of selenium oxychloride and potassium fluoride. [3] 2 KF + SeOCl 2 → 2 KCl + SeOF 2. It can also be produced by the reaction of selenium tetrafluoride with water or selenium dioxide. [2] SeF 4 + H 2 O → SeOF 2 + 2 HF SeF 4 + SeO 2 → 2 SeOF 2
Selenium fluoride may refer to: Selenium tetrafluoride (selenium(IV) fluoride), SeF 4; Selenium hexafluoride (selenium(VI) fluoride), SeF 6
Selenium dibromide – SeBr 2; Selenium dioxide – SeO 2; Selenium disulfide – SeS 2; Selenium hexafluoride – SeF 6; Selenium hexasulfide – Se 2 S 6; Selenium oxybromide – SeOBr 2; Selenium oxydichloride – SeOCl 2; Selenium tetrachloride – SeCl 4; Selenium tetrafluoride – SeF 4; Selenium trioxide – SeO 3; Selenoyl fluoride ...