Search results
Results from the WOW.Com Content Network
Aldehyde structure. In organic chemistry, an aldehyde (/ ˈ æ l d ɪ h aɪ d /) is an organic compound containing a functional group with the structure R−CH=O. [1] The functional group itself (without the "R" side chain) can be referred to as an aldehyde but can also be classified as a formyl group. Aldehydes are a common motif in many ...
The alpha proton is acidic and can be abstracted by a strong base such as butyl lithium and subsequently alkylated by an alkyl halide . In the next step the nitrogen to carbon double bond is reduced with sodium borohydride and the resulting oxazine (a hemiaminal) hydrolyzed with water and oxalic acid to the aldehyde.
The nitrogen atom can be attached to a hydrogen or an organic group (R). The carbon atom has two additional single bonds. [1] [2] Imines are common in synthetic and naturally occurring compounds and they participate in many reactions. [3] Distinction is sometimes made between aldimines and ketimines, derived from aldehydes and ketones ...
Ethers (R−O−R) consist of an oxygen atom between the two attached carbon chains. The shorter of the two chains becomes the first part of the name with the -ane suffix changed to -oxy, and the longer alkane chain becomes the suffix of the name of the ether. Thus, CH 3 OCH 3 is methoxymethane, and CH 3 OCH 2 CH 3 is methoxyethane (not ...
The original Betti base synthesized from 2-naphthol and the imine produced from the reaction of benzaldehyde and ammonia. The product of the Betti reaction is called the Betti base. The stereochemistry of the base was resolved into two isomers by using tartaric acid. Uses for the Betti base and its derivatives include: [1] [3] [4]
In organic chemistry, the Schmidt reaction is an organic reaction in which an azide reacts with a carbonyl derivative, usually an aldehyde, ketone, or carboxylic acid, under acidic conditions to give an amine or amide, with expulsion of nitrogen.
The reaction of NH 2 OH with an aldehyde or ketone produces an oxime. R 2 C=O + NH 2 OH → R 2 C=N−OH + H 2 O This reaction can be useful in the purification of ketones and aldehydes: if hydroxylamine is added to an aldehyde or ketone in solution, an oxime forms, which generally precipitates from solution; heating the precipitate with ...
It contains a double-bonded oxygen atom and an organyl group (R−C=O) or hydrogen in the case of formyl group (H−C=O). In organic chemistry, the acyl group (IUPAC name alkanoyl if the organyl group is alkyl) is usually derived from a carboxylic acid, in which case it has the formula R−C(=O)−, where R represents an organyl group or hydrogen.