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A stationary object (or set of objects) is in "static equilibrium," which is a special case of mechanical equilibrium. A paperweight on a desk is an example of static equilibrium. Other examples include a rock balance sculpture, or a stack of blocks in the game of Jenga , so long as the sculpture or stack of blocks is not in the state of ...
For non-equilibrium thermodynamics, a suitable set of identifying state variables includes some macroscopic variables, for example a non-zero spatial gradient of temperature, that indicate departure from thermodynamic equilibrium. Such non-equilibrium identifying state variables indicate that some non-zero flow may be occurring within the ...
In control engineering and other areas of science and engineering, state variables are used to represent the states of a general system. The set of possible combinations of state variable values is called the state space of the system. The equations relating the current state of a system to its most recent input and past states are called the ...
This basic stability requirement, and similar ones for other conjugate pairs of variables, is violated in analytic models of first order phase transitions. The most famous case is the van der Waals equation, [2] [3] = / / where ,, are dimensional constants. This violation is not a defect, rather it is the origin of the observed discontinuity in ...
An equilibrium state is mathematically ascertained by seeking the extrema of a thermodynamic potential function, whose nature depends on the constraints imposed on the system. For example, a chemical reaction at constant temperature and pressure will reach equilibrium at a minimum of its components' Gibbs free energy and a maximum of their entropy.
Elastic energy of or within a substance is static energy of configuration. It corresponds to energy stored principally by changing the interatomic distances between nuclei. Thermal energy is the randomized distribution of kinetic energy within the material, resulting in statistical fluctuations of the material about the equilibrium ...
Statical indeterminacy, however, is the existence of a non-trivial (non-zero) solution to the homogeneous system of equilibrium equations. It indicates the possibility of self-stress (stress in the absence of an external load) that may be induced by mechanical or thermal action. Mathematically, this requires a stiffness matrix to have full rank.
In other words, the system is dynamically connected, by a movable boundary, to a constant-pressure reservoir. An isochoric process is one in which the volume is held constant, with the result that the mechanical PV work done by the system will be zero. On the other hand, work can be done isochorically on the system, for example by a shaft that ...