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Ca 5 (PO 4) 3 OH + 5 H 2 SO 4 → 3 H 3 PO 4 + 5 CaSO 4 + H 2 O Ca 5 (PO 4) 3 F + 5 H 2 SO 4 → 3 H 3 PO 4 + 5 CaSO 4 + HF. Calcium sulfate (gypsum, CaSO 4) is a by-product, which is removed as phosphogypsum. The hydrogen fluoride (HF) gas is streamed into a wet (water) scrubber producing hydrofluoric acid. In both cases the phosphoric acid ...
Since the ends are condensed, its formula has one less H 2 O (water) than tripolyphosphoric acid. The general formula of a phosphoric acid is H n−2x+2 P n O 3n−x+1, where n is the number of phosphorus atoms and x is the number of fundamental cycles in the molecule's structure; that is, the minimum number of bonds that would have to be ...
It most commonly means orthophosphate, a derivative of orthophosphoric acid, a.k.a. phosphoric acid H 3 PO 4. The phosphate or orthophosphate ion [PO 4] 3− is derived from phosphoric acid by the removal of three protons H +. Removal of one proton gives the dihydrogen phosphate ion [H 2 PO 4] − while removal of two protons gives the hydrogen ...
It is a conjugate acid of phosphate [PO 4] 3-and a conjugate base of dihydrogen phosphate [H 2 PO 4] −. It is formed when a pyrophosphate anion [P 2 O 7] 4− reacts with water H 2 O by hydrolysis, which can give hydrogenphosphate: [P 2 O 7] 4− + H 2 O ⇌ 2 [HPO 4] 2−
P 4 + 4 OH − + 4 H 2 O → 4 H 2 PO − 2 + 2 H 2. Any phosphites produced in this step can be selectively precipitated out by treatment with calcium salts. The purified material is then treated with a strong, non-oxidizing acid (often sulfuric acid) to give the free hypophosphorous acid: H 2 PO − 2 + H + → H 3 PO 2. HPA is usually ...
They are oxidized to phosphoric acid or its salts. It reduces solutions of noble metal cations to the metals. When phosphorous acid is treated with a cold solution of mercuric chloride, a white precipitate of mercurous chloride forms: H 3 PO 3 + 2 HgCl 2 + H 2 O → Hg 2 Cl 2 + H 3 PO 4 + 2 HCl. Mercurous chloride is reduced further by ...
The compound is a triprotic acid with acid dissociation constants pK a1 = 1.1, pK a2 = 5.5 and pK a3 = 12.8. In aqueous solutions it slowly undergoes hydrolysis to hydrogen peroxide and phosphoric acid. [7] H 3 PO 5 + H 2 O → H 3 PO 4 + H 2 O 2. With excess water, the hydrolysis can be considered pseudo-first order.
2 (nh 4) 2 hpo 4 + 3 cuo → cu 3 (po 4) 2 + 3 h 2 o + 4 nh 3 In laboratories, copper phosphate is prepared by the addition of phosphoric acid to an alkali copper salt such as copper hydroxide, or basic copper carbonate.
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