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It is a common observation that when oil and water are poured into the same container, they separate into two phases or layers, because they are immiscible.In general, aqueous (or water-based) solutions, being polar, are immiscible with non-polar organic solvents (cooking oil, chloroform, toluene, hexane etc.) and form a two-phase system.
In ternary systems such as microemulsions, where two immiscible phases (water and ‘oil’) are present with a surfactant, the surfactant molecules may form a monolayer at the interface between the oil and water, with the hydrophobic tails of the surfactant molecules dissolved in the oil phase and the hydrophilic head groups in the aqueous phase.
Second, they can form a water-in-oil emulsion, in which water is the dispersed phase and oil is the continuous phase. Multiple emulsions are also possible, including a "water-in-oil-in-water" emulsion and an "oil-in-water-in-oil" emulsion. [1] Emulsions, being liquids, do not exhibit a static internal structure.
The wax also accumulates on cold surfaces (producing, for example, pipeline or heat exchanger fouling) and forms an emulsion or sol with water. Therefore, cloud point indicates the tendency of the oil to plug filters or small orifices at cold operating temperatures. [2] An everyday example of cloud point can be seen in olive oil stored in cold ...
Phase separation is the creation of two distinct phases from a single homogeneous mixture. [1] The most common type of phase separation is between two immiscible liquids, such as oil and water. This type of phase separation is known as liquid-liquid equilibrium.
In a (W/O/W) combination, an immiscible oil phase exists between two separate water phases. In contrast, in an (O/W/O) combination the immiscible water phase separates two different oil phases. [1] Image A is (O/W) emulsion. Image B is a (W/O) emulsion. Image C is a W/O/W multiple emulsion group. Image D is a (O/W/O) multiple emulsion group.
Demulsifiers, or emulsion breakers, are a class of specialty chemicals used to separate emulsions, for example, water in oil. They are commonly used in the processing of crude oil, which is typically produced along with significant quantities of saline water. This water (and salt) must be removed from the crude oil prior to refining.
In water-in-oil emulsions – use emulsifying agents that are more soluble in oil than in water (Low HLB surfactants). Bancroft's rule suggests that the type of emulsion is dictated by the emulsifier and that the emulsifier should be soluble in the continuous phase. This empirical observation can be rationalized by considering the interfacial ...