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Hexamethylbenzene, also known as mellitene, is a hydrocarbon with the molecular formula C 12 H 18 and the condensed structural formula C 6 (CH 3) 6. It is an aromatic compound and a derivative of benzene , where benzene's six hydrogen atoms have each been replaced by a methyl group .
Discounting isomers that are equivalent under rotations, there are nine isomers that differ by this criterion, and behave as different stable substances (two of them being enantiomers of each other). The most common one in nature ( myo -inositol) has the hydroxyls on carbons 1, 2, 3 and 5 on the same side of that plane, and can therefore be ...
Enolization is an example of isomerization, as is tautomerization. [2] When the isomerization occurs intramolecularly it may be called a rearrangement reaction. [citation needed] When the activation energy for the isomerization reaction is sufficiently small, both isomers will exist in a temperature-dependent equilibrium with each other.
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The Curtin–Hammett principle is a principle in chemical kinetics proposed by David Yarrow Curtin and Louis Plack Hammett.It states that, for a reaction that has a pair of reactive intermediates or reactants that interconvert rapidly (as is usually the case for conformational isomers), each going irreversibly to a different product, the product ratio will depend both on the difference in ...
Halogenating a hydrocarbon produces something that is not a hydrocarbon. It is a very common and useful process. Hydrocarbons with the same molecular formula but different structural formulae are called structural isomers. [1]: 625 As given in the example of 3-methylhexane and its higher homologues, branched hydrocarbons can be chiral.
Heteroarenes are aromatic compounds, where at least one methine or vinylene (-C= or -CH=CH-) group is replaced by a heteroatom: oxygen, nitrogen, or sulfur. [3] Examples of non-benzene compounds with aromatic properties are furan, a heterocyclic compound with a five-membered ring that includes a single oxygen atom, and pyridine, a heterocyclic compound with a six-membered ring containing one ...
Alkylbenzene isomers can be differentiated by observing the position of alkyl substituents on the benzene ring using chemical ionization-proton exchange mass spectrometry. Conventional GC-MS yields limited results because the isomers have identical molecular weight and substituents.