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Proline organocatalysis is the use of proline as an organocatalyst in organic chemistry. This theme is often considered the starting point for the area of organocatalysis, even though early discoveries went unappreciated. [1] Modifications, such as MacMillan’s catalyst and Jorgensen's catalysts, proceed with excellent stereocontrol. [2]: 5574 [3]
Furthermore, proline is rarely found in α and β structures as it would reduce the stability of such structures, because its side chain α-nitrogen can only form one nitrogen bond. Additionally, proline is the only amino acid that does not form a red-purple colour when developed by spraying with ninhydrin for uses in chromatography. Proline ...
In this reaction, naturally occurring chiral proline is the chiral catalyst in an aldol reaction. The starting material is an achiral triketone and it requires just 3% of proline to obtain the reaction product, a ketol in 93% enantiomeric excess. This is the first example of an amino acid-catalyzed asymmetric aldol reaction. [16] [17]
The Hajos–Parrish–Eder–Sauer–Wiechert and Barbas-List [1] reactions in organic chemistry are a family of proline-catalysed asymmetric aldol reactions.. In the 1970s, two research groups discovered (and published) almost simultaneously their discoveries of two related intramolecular reactions: Zoltan Hajos and David Parrish at Hoffmann-La Roche [2] [3] and Rudolf Wiechert et al at ...
Soda and juices wreak havoc on blood-sugar levels. Add some interest to seltzer by squeezing in fresh citrus, opting for flavored (but not sweetened) versions, or infusing with a sprig of fresh herbs.
Breakfast (387 calories) 1 serving Mascarpone & Berries Toast. 2 eggs, scrambled. A.M. Snack (410 calories) 1 serving Anti-Inflammatory Cherry-Spinach Smoothie. Lunch (401 calories) 1 serving ...
Nutrition: 45 calories, 0.5 g fat (0 g saturated fat), 430 mg sodium, 10 g carbs (2 g fiber, 5 g sugar), 2 g protein. With 45 calories per serving and less than 1 gram of total fat, Barilla makes ...
postprandial glucose test (PC): 2 hours after eating [1] random glucose test; Some laboratory tests don't measure glucose levels directly from body fluids or tissues but still indicate elevated blood sugar levels. Such tests measure the levels of glycated hemoglobin, other glycated proteins, 1,5-anhydroglucitol etc. from blood. [1]
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