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Mass transfer coefficients can be estimated from many different theoretical equations, correlations, and analogies that are functions of material properties, intensive properties and flow regime (laminar or turbulent flow). Selection of the most applicable model is dependent on the materials and the system, or environment, being studied.
Here, is the overall mass transfer coefficient, which could be determined by empirical correlations, is the surface area for mass transfer (particularly relevant in membrane-based separations), and ˙ is the mass flowrate of bulk fluid (e.g., mass flowrate of air in an application where water vapor is being separated from the air mixture). At ...
This rate can be quantified through the calculation and application of mass transfer coefficients for an overall process. These mass transfer coefficients are typically published in terms of dimensionless numbers, often including Péclet numbers, Reynolds numbers, Sherwood numbers, and Schmidt numbers, among others. [2] [3] [4]
The Sherwood number (Sh) (also called the mass transfer Nusselt number) is a dimensionless number used in mass-transfer operation. It represents the ratio of the total mass transfer rate ( convection + diffusion) to the rate of diffusive mass transport, [ 1 ] and is named in honor of Thomas Kilgore Sherwood .
For best accuracy, n should be adjusted where correlations have a different exponent. We can take this further by substituting into this equation the definitions of the heat transfer coefficient, mass transfer coefficient, and Lewis number, yielding: = =
This equation permits the prediction of an unknown transfer coefficient when one of the other coefficients is known. The analogy is valid for fully developed turbulent flow in conduits with Re > 10000, 0.7 < Pr < 160, and tubes where L/d > 60 (the same constraints as the Sieder–Tate correlation). The wider range of data can be correlated by ...
mass transfer (advection–diffusion problems; total momentum transfer to diffusive mass transfer) Prandtl number: Pr = = heat transfer (ratio of viscous diffusion rate over thermal diffusion rate) Pressure coefficient: C P
In the context of species or mass transfer, the Péclet number is the product of the Reynolds number and the Schmidt number (Re × Sc). In the context of the thermal fluids, the thermal Péclet number is equivalent to the product of the Reynolds number and the Prandtl number (Re × Pr). The Péclet number is defined as: