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Polybutylene terephthalate (PBT) is a thermoplastic engineering polymer that is used as an insulator in the electrical and electronics industries. [2] It is a thermoplastic (semi-)crystalline polymer , and a type of polyester .
The pre-equilibrium and re-initiation steps are completed very early in the polymerization meaning that the major product of the reaction (the RAFT polymer chains, RAFT-P n), all start growing at approximately the same time. The forward and reverse reactions of the main RAFT equilibrium are fast, favoring equal growth opportunities amongst the ...
The Carothers equation is an effective method for calculating the degree of polymerization for stoichiometrically balanced reactions. [1] However, the Carothers equation is limited to branched systems, describing the degree of polymerization only at the onset of cross-linking.
In polymer chemistry, chain transfer is a polymerization reaction by which the activity of a growing polymer chain is transferred to another molecule: [1] [2] + + where • is the active center, P is the initial polymer chain, X is the end group, and R is the substituent to which the active center is transferred.
In polymer chemistry, polymerization (American English), or polymerisation (British English), is a process of reacting monomer molecules together in a chemical reaction to form polymer chains or three-dimensional networks. [1] [2] [3] There are many forms of polymerization [4] and different systems exist to categorize them. IUPAC definition for ...
Random graph theory of gelation is a mathematical theory for sol–gel processes.The theory is a collection of results that generalise the Flory–Stockmayer theory, and allow identification of the gel point, gel fraction, size distribution of polymers, molar mass distribution and other characteristics for a set of many polymerising monomers carrying arbitrary numbers and types of reactive ...
There is a mode of polymerization referred to as reversible-deactivation polymerization which is distinct from living polymerization, despite some common features. Living polymerization requires a complete absence of termination reactions, whereas reversible-deactivation polymerization may contain a similar fraction of termination as conventional polymerization with the same concentration of ...
The Mayo–Lewis equation or copolymer equation in polymer chemistry describes the distribution of monomers in a copolymer. It was proposed by Frank R. Mayo and Frederick M. Lewis . [ 1 ]