Search results
Results from the WOW.Com Content Network
Buffer capacity rises to a local maximum at pH = pK a. The height of this peak depends on the value of pK a. Buffer capacity is negligible when the concentration [HA] of buffering agent is very small and increases with increasing concentration of the buffering agent. [3] Some authors show only this region in graphs of buffer capacity. [2]
It is possible to envision three-dimensional (3D) graphs showing three thermodynamic quantities. [12] [13] For example, for a single component, a 3D Cartesian coordinate type graph can show temperature (T) on one axis, pressure (p) on a second axis, and specific volume (v) on a third. Such a 3D graph is sometimes called a p–v–T diagram. The ...
This page was last edited on 6 April 2017, at 05:47 (UTC).; Text is available under the Creative Commons Attribution-ShareAlike 4.0 License; additional terms may ...
For example, heat capacity is an extensive property of a system. Dividing heat capacity, , by the mass of the system gives the specific heat capacity, , which is an intensive property. When the extensive property is represented by an upper-case letter, the symbol for the corresponding intensive property is usually represented by a lower-case ...
In thermodynamics, a critical point (or critical state) is the end point of a phase equilibrium curve. One example is the liquid–vapor critical point, the end point of the pressure–temperature curve that designates conditions under which a liquid and its vapor can coexist.
The heat capacity is = = . In general, consider the extensive variable X and intensive variable Y where X and Y form a pair of conjugate variables . In ensembles where Y is fixed (and X is allowed to fluctuate), then the average value of X will be: X = ± ∂ ln Z ∂ β Y . {\displaystyle \langle X\rangle =\pm {\frac {\partial \ln Z ...
HEPES (4-(2-hydroxyethyl)-1-piperazineethanesulfonic acid) is a zwitterionic sulfonic acid buffering agent.It is one of the twenty Good's buffers.HEPES is widely used in cell culture, largely because it is better at maintaining physiological pH despite changes in carbon dioxide concentration (produced by aerobic respiration) when compared to bicarbonate buffers, which are also commonly used in ...
Reduced specific heat for KCl, TiO2, and graphite, compared with the Debye theory based on elastic measurements (solid lines) [1]. In thermodynamics and solid-state physics, the Debye model is a method developed by Peter Debye in 1912 to estimate phonon contribution to the specific heat (heat capacity) in a solid. [2]