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The general notation for hydrogen bonding is Dn−H···Ac, where the solid line represents a polar covalent bond, and the dotted or dashed line indicates the hydrogen bond. [6] The most frequent donor and acceptor atoms are nitrogen (N), oxygen (O), and fluorine (F), due to their high electronegativity and ability to engage in stronger ...
A solid with extensive hydrogen bonding will be considered a molecular solid, yet strong hydrogen bonds can have a significant degree of covalent character. As noted above, covalent and ionic bonds form a continuum between shared and transferred electrons; covalent and weak bonds form a continuum between shared and unshared electrons.
Inclusion Compound: A complex in which one component (the host) forms a cavity or, in the case of a crystal, a crystal lattice containing spaces in the shape of long tunnels or channels in which molecular entities of a second chemical species (the guest) are located. There is no covalent bonding between guest and host, the attraction being ...
They are composed entirely of single bonds and are saturated with hydrogen. The formula for acyclic saturated hydrocarbons (i.e., alkanes) is C n H 2n+2. [1]: 623 The most general form of saturated hydrocarbons, (whether linear or branched species, and whether with or without one or more rings) is C n H 2n+2(1-r), where r is the
The lone electron pair on the nitrogen atom (N) in ammonia, represented as a line above the N, forms a coordinate bond with a proton (H +). After that, all four N−H bonds are equivalent, being polar covalent bonds. The ion has a tetrahedral structure and is isoelectronic with methane and the borohydride anion.
For intermolecular hydrogen bonds the δ+ hydrogen interacts with a δ- on an adjacent molecule. Examples of molecular solids that hydrogen bond are water, amino acids , and acetic acid. [ 3 ] [ 5 ] [ 8 ] [ 10 ] For acetic acid, the hydrogen (δ+) on the alcohol moiety of the carboxylic acid hydrogen bonds with other the carbonyl moiety (δ ...
In an alkane, each carbon atom is sp 3-hybridized with 4 sigma bonds (either C–C or C–H), and each hydrogen atom is joined to one of the carbon atoms (in a C–H bond). The longest series of linked carbon atoms in a molecule is known as its carbon skeleton or carbon backbone.
In the A-U Hoogsteen base pair, the adenine is rotated 180° about the glycosidic bond, resulting in an alternative hydrogen bonding scheme which has one hydrogen bond in common with the Watson-Crick base pair (adenine N6 and thymine N4), while the other hydrogen bond, instead of occurring between adenine N1 and thymine N3 as in the Watson ...