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Gibbs free energy is a thermodynamic state function that measures the energy available for a system to do work, and is given by the formula G = H – TS, where H is enthalpy, T is temperature, and S is entropy.
The ancient Greek understanding of physics was limited to the statics of simple machines (the balance of forces), and did not include dynamics or the concept of work. During the Renaissance the dynamics of the Mechanical Powers, as the simple machines were called, began to be studied from the standpoint of how far they could lift a load, in addition to the force they could apply, leading ...
Thermodynamic work is one of the principal kinds of process by which a thermodynamic system can interact with and transfer energy to its surroundings. This results in externally measurable macroscopic forces on the system's surroundings, which can cause mechanical work, to lift a weight, for example, [1] or cause changes in electromagnetic, [2] [3] [4] or gravitational [5] variables.
The maximum work is thus regarded as the diminution of the free, or available, energy of the system (Gibbs free energy G at T = constant, P = constant or Helmholtz free energy F at T = constant, V = constant), whilst the heat given out is usually a measure of the diminution of the total energy of the system (internal energy).
Energy – in physics, this is an indirectly observed quantity often understood as the ability of a physical system to do work on other physical systems. [ 1 ] [ 2 ] Since work is defined as a force acting through a distance (a length of space), energy is always equivalent to the ability to exert force (a pull or a push) against an object that ...
The work can be done, for example, by electrochemical devices (electrochemical cells) or different metals junctions [clarification needed] generating an electromotive force. Electric field work is formally equivalent to work by other force fields in physics, [1] and the formalism for electrical work is identical to that of mechanical work.
Power is the rate with respect to time at which work is done; it is the time derivative of work: =, where P is power, W is work, and t is time. We will now show that the mechanical power generated by a force F on a body moving at the velocity v can be expressed as the product: P = d W d t = F ⋅ v {\displaystyle P={\frac {dW}{dt}}=\mathbf {F ...
Therefore, only relative free energy values, or changes in free energy, are physically meaningful. The free energy is the portion of any first-law energy that is available to perform thermodynamic work at constant temperature, i.e., work mediated by thermal energy. Free energy is subject to irreversible loss in the course of such work. [1]