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Non-chlorinated brake cleaners use hydrocarbons as a main component; it will either be a low-boiling aliphatic compound or higher-boiling hydrocarbon mixture. Aromatics like benzene, toluene or xylene may also be used. [6] The hydrocarbons used are sometimes made by hydrogenation from naphtha. The lipophilic liquids dissolve fat-soluble ...
Tetrachloroethylene is regarded as a toxic substance, a human health hazard, and an environmental hazard. [ 5 ] [ 7 ] In 2020, the United States Environmental Protection Agency stated that "tetrachloroethylene exposure may harm the nervous system, liver, kidneys, and reproductive system, and may be harmful to unborn children", and reported that ...
First, ethylene is chlorinated over a ferric chloride catalyst to produce 1,2-dichloroethane: CH 2 =CH 2 + Cl 2 → ClCH 2 CH 2 Cl. When heated to around 400 °C with additional chlorine, 1,2-dichloroethane is converted to trichloroethylene: ClCH 2 CH 2 Cl + 2 Cl 2 → ClCH=CCl 2 + 3 HCl. This reaction can be catalyzed by a variety of substances.
CFC-113’s low flammability and low toxicity made it ideal for use as a cleaner for delicate electrical equipment, fabrics, and metals. It would not harm the product it was cleaning, ignite with a spark or react with other chemicals. [13]
1,1,1-Trichloroethane is an excellent solvent for many organic compounds and also one of the least toxic of the chlorinated hydrocarbons.It is generally considered non-polar, but owing to the good polarizability of the chlorine atoms, it is a superior solvent for organic compounds that do not dissolve well in hydrocarbons such as hexane.
Aqueous cleaners have advantages as regards to particle and polar contaminants and only require higher inputs of mechanical and thermal energy to be effective, whereas solvents more easily remove oils and greases but have health and environmental risks. In addition, most solvents are flammable, creates fire and explosion hazards.
A 2008 study indicated that sodium hypochlorite and organic chemicals (e.g., surfactants, fragrances) contained in several household cleaning products can react to generate chlorinated volatile organic compounds (VOCs). [12] These chlorinated compounds are emitted during cleaning applications, some of which are toxic and probable human carcinogens.
Brakleen, a tetrachloroethylene (PERC)-based brake cleaner, is one of CRC's signature products. It has gained a cult following due to its dissolving power and has been used off-label for many other purposes, a practice strongly discouraged by health experts and the product's own warning labels.
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