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  2. Exothermic reaction - Wikipedia

    en.wikipedia.org/wiki/Exothermic_reaction

    An energy profile of an exothermic reaction. In an exothermic reaction, by definition, the enthalpy change has a negative value: ΔH = H products - H reactants < 0. where a larger value (the higher energy of the reactants) is subtracted from a smaller value (the lower energy of the products). For example, when hydrogen burns: 2H 2 (g) + O 2 (g ...

  3. Nitroethane - Wikipedia

    en.wikipedia.org/wiki/Nitroethane

    Nitroethane is an organic compound having the chemical formula C 2 H 5 NO 2. Similar in many regards to nitromethane , nitroethane is an oily liquid at standard temperature and pressure. Pure nitroethane is colorless and has a fruity odor.

  4. Nef reaction - Wikipedia

    en.wikipedia.org/wiki/Nef_reaction

    Nef's original protocol, using concentrated sulfuric acid, has been described as "violent". [9] Strong-acid hydrolysis without the intermediate salt stage results in the formation of carboxylic acids and hydroxylamine salts, [ citation needed ] but Lewis acids such as tin(IV) chloride [ 10 ] and iron(III) chloride [ 11 ] give a clean hydrolysis.

  5. Exothermic process - Wikipedia

    en.wikipedia.org/wiki/Exothermic_process

    An exothermic thermite reaction using iron(III) oxide. The sparks flying outwards are globules of molten iron trailing smoke in their wake. Some examples of exothermic processes are: [14] Combustion of fuels such as wood, coal and oil/petroleum; The thermite reaction [15] The reaction of alkali metals and other highly electropositive metals ...

  6. Monopropellant - Wikipedia

    en.wikipedia.org/wiki/Monopropellant

    Monopropellants [1] are propellants consisting of chemicals that release energy through exothermic chemical decomposition. The molecular bond energy of the monopropellant is released usually through use of a catalyst. This can be contrasted with bipropellants that release energy through the chemical reaction between an oxidizer and a fuel.

  7. Basis set (chemistry) - Wikipedia

    en.wikipedia.org/wiki/Basis_set_(chemistry)

    The original Pople notation added "*" to indicate that all "heavy" atoms (everything but H and He) have a small set of polarization functions added to the basis (in the case of carbon, a set of 3d orbital functions). The "**" notation indicates that all "light" atoms also receive polarization functions (this adds a set of 2p orbitals to the ...

  8. Enthalpy change of solution - Wikipedia

    en.wikipedia.org/wiki/Enthalpy_change_of_solution

    The energy released by the solvation of the ammonium ions and nitrate ions is less than the energy absorbed in breaking up the ammonium nitrate ionic lattice and the attractions between water molecules. Dissolving potassium hydroxide is exothermic, as more energy is released during solvation than is used in breaking up the solute and solvent.

  9. Hess's law - Wikipedia

    en.wikipedia.org/wiki/Hess's_law

    The concepts of Hess's law can be expanded to include changes in entropy and in Gibbs free energy, since these are also state functions. The Bordwell thermodynamic cycle is an example of such an extension that takes advantage of easily measured equilibria and redox potentials to determine experimentally inaccessible Gibbs free energy values.