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A molecular sieve is a material with pores (voids or holes), having uniform size comparable to that of individual molecules, linking the interior of the solid to its exterior. These materials embody the molecular sieve effect, the preferential sieving of molecules larger than the pores.
Classic oxygen concentrators use two-bed molecular sieves; newer concentrators use multi-bed molecular sieves. The advantage of the multi-bed technology is the increased availability and redundancy, as the 10 L/min molecular sieves are staggered and multiplied on several platforms. With this, over 960 L/min can be produced.
With continuous flow units, oxygen delivery is measured in LPM (liters per minute). Providing continuous flow requires a larger molecular sieve and pump/motor assembly, and additional electronics. This increases the device’s size and weight (approximately 18–20 lbs). [13]
VPSA systems apply pressurized gas to the separation process and also apply a vacuum to the purge gas. VPSA systems, like one of the portable oxygen concentrators, are among the most efficient systems measured on customary industry indices, such as recovery (product gas out/product gas in) and productivity (product gas out/mass of sieve material).
Size-exclusion chromatography, also known as molecular sieve chromatography, [1] is a chromatographic method in which molecules in solution are separated by their shape, and in some cases size. [2] It is usually applied to large molecules or macromolecular complexes such as proteins and industrial polymers . [ 3 ]
The typical molecular sieve used is a synthetic zeolite with a pore diameter around 0.4 nanometer ( Type 4A ) and a surface area of about 500 m 2 /g. The sorption pump contains between 300 g and 1.2 kg of molecular sieve. A 15-liter system will be pumped down to about 10 −2 mbar by 300 g molecular sieve. [1]
A characteristic operation for a vacuum oven is the activation or regeneration of molecular sieves. [1] [2] Vacuum furnaces are related devices that operate at much higher temperatures and much lower pressures. The acetylacetonate complex Mn(acac) 2 is obtained by vacuum drying the yellow dihydrate Mn(acac) 2 (H 2 O) 2. [3]
A nitrogen generator Bottle of 4Å molecular sieves. Pressure swing adsorption provides separation of oxygen or nitrogen from air without liquefaction. The process operates around ambient temperature; a zeolite (molecular sponge) is exposed to high pressure air, then the air is released and an adsorbed film of the desired gas is released.
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