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Equal masses of iron (Fe) and sulfur (S) react to form iron sulfide (FeS), but because of its higher atomic weight, iron is the limiting reagent and once all the iron is consumed some sulfur remains unreacted
Organic chemistry is a subdiscipline within chemistry involving the scientific study of the structure, properties, and reactions of organic compounds and organic materials, i.e., matter in its various forms that contain carbon atoms. [1]
Triphosgene is used as a reagent in organic synthesis as a source of CO 2+. It behaves like phosgene, to which it cracks thermally: OC(OCCl 3) 2 ⇌ 3 OCCl 2. Alcohols are converted to carbonates. Primary and secondary amines are converted to ureas and isocyanates. [6] [7] [9] [10] Triphosgene has been used to synthesize chlorides. [8]
Another example is the unimolecular nucleophilic substitution (S N 1) reaction in organic chemistry, where it is the first, rate-determining step that is unimolecular. A specific case is the basic hydrolysis of tert-butyl bromide (t-C 4 H 9 Br) by aqueous sodium hydroxide. The mechanism has two steps (where R denotes the tert-butyl radical t-C ...
The following outline is provided as an overview of and topical guide to organic chemistry: . Organic chemistry is the scientific study of the structure, properties, composition, reactions, and preparation (by synthesis or by other means) of carbon-based compounds, hydrocarbons, and their derivatives.
The split and pool (split-mix) synthesis is a method in combinatorial chemistry that can be used to prepare combinatorial compound libraries. It is a stepwise, highly efficient process realized in repeated cycles.
4-Hydroxy-TEMPO or TEMPOL, formally 4-hydroxy-2,2,6,6-tetramethylpiperidin-1-oxyl, is a heterocyclic compound.Like the related TEMPO, it is used as a catalyst and chemical oxidant by virtue of being a stable aminoxyl radical.
In chemistry, transition state theory (TST) explains the reaction rates of elementary chemical reactions. The theory assumes a special type of chemical equilibrium (quasi-equilibrium) between reactants and activated transition state complexes. [1] TST is used primarily to understand qualitatively how chemical reactions take place.
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