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Archaeological materials, such as bone, organic residues, hair, or sea shells, can serve as substrates for isotopic analysis. Carbon, nitrogen and zinc isotope ratios are used to investigate the diets of past people; these isotopic systems can be used with others, such as strontium or oxygen, to answer questions about population movements and cultural interactions, such as trade.
A mnemonic is a memory aid used to improve long-term memory and make the process of consolidation easier. Many chemistry aspects, rules, names of compounds, sequences of elements, their reactivity, etc., can be easily and efficiently memorized with the help of mnemonics.
Owing to both of these advantages, the method of isotope dilution is regarded among chemistry measurement methods of the highest metrological standing. [1] Isotopes are variants of a particular chemical element which differ in neutron number. All isotopes of a given element have the same number of protons in each atom.
A nuclide is a species of an atom with a specific number of protons and neutrons in the nucleus, for example, carbon-13 with 6 protons and 7 neutrons. The nuclide concept (referring to individual nuclear species) emphasizes nuclear properties over chemical properties, whereas the isotope concept (grouping all atoms of each element) emphasizes chemical over nuclear.
Naturally occurring krypton in Earth's atmosphere is composed of five stable isotopes, plus one isotope (78 Kr) with such a long half-life (9.2×10 21 years) that it can be considered stable. (This isotope has the third-longest known half-life among all isotopes for which decay has been observed; it undergoes double electron capture to 78 Se).
An isotopologue with a doubly substituted bond is therefore slightly more thermodynamically stable, which will tend to produce a higher abundance of the doubly substituted (or “clumped”) species than predicted by the statistical abundance of each heavy isotope (known as a stochastic distribution of isotopes).
In contrast, the proton numbers for which there are no stable isotopes are 43, 61, and 83 or more (83, 90, 92, and perhaps 94 have primordial radionuclides). [3] This is related to nuclear magic numbers , the number of nucleons forming complete shells within the nucleus, e.g. 2, 8, 20, 28, 50, 82, and 126.
Isotopocules are isotopically substituted molecules, which differ only in their isotopic composition or their isotopes' intramolecular position. [1] " Isotopocule" is also an umbrella term for the more specific terms " isotopologue " and " isotopomer ", coined by Jan Kaiser and Thomas Röckmann in 2008.