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  2. Descriptor (chemistry) - Wikipedia

    en.wikipedia.org/wiki/Descriptor_(Chemistry)

    See: E-Z notation Violet leaf aldehyde, systematic name (E,Z)-nona-2,6-dienal, is a compound having one (E)- and one (Z)-configured double bond. The descriptors (E) (from German entgegen, 'opposite') and (Z) (from German zusammen, 'together') are used to provide a distinct description of the substitution pattern for alkenes, cumulenes or other double bond systems such as oximes.

  3. Rotamer - Wikipedia

    en.wikipedia.org/wiki/Rotamer

    syn/anti peri/clinal. a torsion angle between 0° and ±90° is called syn (s) a torsion angle between ±90° and 180° is called anti (a) a torsion angle between 30° and 150° or between −30° and −150° is called clinal (c) a torsion angle between 0° and ±30° or ±150° and 180° is called periplanar (p)

  4. Syn and anti addition - Wikipedia

    en.wikipedia.org/wiki/Syn_and_anti_addition

    The concepts of syn and anti addition are used to characterize the different reactions of organic chemistry by reflecting the stereochemistry of the products in a reaction. The type of addition that occurs depends on multiple different factors of a reaction, and is defined by the final orientation of the substituents on the parent molecule .

  5. Aldol reaction - Wikipedia

    en.wikipedia.org/wiki/Aldol_reaction

    The disposition of the formed stereocenters is deemed syn or anti, depending if they are on the same or opposite sides of the main chain: Syn and anti products from an aldol (addition) reaction. The principal factor determining an aldol reaction's stereoselectivity is the enolizing metal counterion.

  6. Anti-periplanar - Wikipedia

    en.wikipedia.org/wiki/Anti-periplanar

    Anti-periplanar geometry will put a bonding orbital and an anti-bonding orbital approximately parallel to each other, or syn-periplanar. Figure 6 is another representation of 2-chloro-2,3-dimethylbutane (Figure 5), showing the C–H bonding orbital, σ C–H, and the C–Cl anti-bonding orbital, σ* C–Cl, syn-periplanar.

  7. Retrosynthetic analysis - Wikipedia

    en.wikipedia.org/wiki/Retrosynthetic_analysis

    Retrosynthetic analysis is a technique for solving problems in the planning of organic syntheses.This is achieved by transforming a target molecule into simpler precursor structures regardless of any potential reactivity/interaction with reagents.

  8. Gauche effect - Wikipedia

    en.wikipedia.org/wiki/Gauche_effect

    The gauche effect is very sensitive to solvent effects, due to the large difference in polarity between the two conformers.For example, 2,3-dinitro-2,3-dimethylbutane, which in the solid state exists only in the gauche conformation, prefers the gauche conformer in benzene solution by a ratio of 79:21, but in carbon tetrachloride, it prefers the anti conformer by a ratio of 58:42. [9]

  9. Syngas to gasoline plus - Wikipedia

    en.wikipedia.org/wiki/Syngas_to_gasoline_plus

    The main product of the Fischer–Tropsch process, synthetic crude oil, requires additional refining to produce fuel products such as diesel fuel or gasoline. This refining typically adds additional costs, causing some industry leaders to label the economics of commercial-scale Fischer–Tropsch processes as challenging.

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    syn vs anti diagram meaning in research process pdf full text 1831 free