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The density of dry ice increases with decreasing temperature and ranges between about 1.55 and 1.7 g/cm 3 (97 and 106 lb/cu ft) below 195 K (−78 °C; −109 °F). [3] The low temperature and direct sublimation to a gas makes dry ice an effective coolant, since it is colder than water ice and leaves no residue as it changes state. [4]
Comparison of phase diagrams of carbon dioxide (red) and water (blue) showing the carbon dioxide sublimation point (middle-left) at 1 atmosphere. As dry ice is heated, it crosses this point along the bold horizontal line from the solid phase directly into the gaseous phase. Water, on the other hand, passes through a liquid phase at 1 atmosphere.
Jets of liquid carbon dioxide. Liquid carbon dioxide is the liquid state of carbon dioxide (CO 2), which cannot occur under atmospheric pressure.It can only exist at a pressure above 5.1 atm (5.2 bar; 75 psi), under 31.1 °C (88.0 °F) (temperature of critical point) and above −56.6 °C (−69.9 °F) (temperature of triple point). [1]
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Familiar examples are the melting of ice or the boiling of water (the water does not instantly turn into vapor, but forms a turbulent mixture of liquid water and vapor bubbles). Yoseph Imry and Michael Wortis showed that quenched disorder can broaden a first-order transition. That is, the transformation is completed over a finite range of ...
Ice VII is the only disordered phase of ice that can be ordered by simple cooling. (While ice I h theoretically transforms into proton-ordered ice XI on geologic timescales, in practice it is necessary to add small amounts of KOH catalyst.) It forms (ordered) ice VIII below 273 K up to ~8 GPa.
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