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A single-displacement reaction, also known as single replacement reaction or exchange reaction, is an archaic concept in chemistry. It describes the stoichiometry of some chemical reactions in which one element or ligand is replaced by an atom or group. [1] [2] [3] It can be represented generically as: + +
Substitution reactions in organic chemistry are classified either as electrophilic or nucleophilic depending upon the reagent involved, whether a reactive intermediate involved in the reaction is a carbocation, a carbanion or a free radical, and whether the substrate is aliphatic or aromatic. Detailed understanding of a reaction type helps to ...
Another example of a double displacement reaction is the reaction of lead(II) nitrate with potassium iodide to form lead(II) iodide and potassium nitrate: + + Forward and backward reactions According to Le Chatelier's Principle , reactions may proceed in the forward or reverse direction until they end or reach equilibrium .
Castigliano's method for calculating displacements is an application of his second theorem, which states: If the strain energy of a linearly elastic structure can be expressed as a function of generalised force Q i then the partial derivative of the strain energy with respect to generalised force gives the generalised displacement q i in the direction of Q i.
A neutralization reaction is a type of double replacement reaction. A neutralization reaction occurs when an acid reacts with an equal amount of a base. This reaction usually produces a salt. One example, hydrochloric acid reacts with disodium iron tetracarbonyl to produce the iron dihydride: 2 HCl + Na 2 Fe(CO) 4 → 2 NaCl + H 2 Fe(CO) 4
Schematic illustration of independent binary collisions between atoms. When the initial recoil/ion mass is low, and the material where the cascade occurs has a low density (i.e. the recoil-material combination has a low stopping power), the collisions between the initial recoil and sample atoms occur rarely, and can be understood well as a sequence of independent binary collisions between atoms.
The two important examples are (i) the internal forces in a rigid body, and (ii) the constraint forces at an ideal joint. Lanczos [1] presents this as the postulate: "The virtual work of the forces of reaction is always zero for any virtual displacement which is in harmony with the given kinematic constraints." The argument is as follows.
Chemical kinetics, also known as reaction kinetics, is the branch of physical chemistry that is concerned with understanding the rates of chemical reactions. It is different from chemical thermodynamics, which deals with the direction in which a reaction occurs but in itself tells nothing about its rate.