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According to experimental evidence from microwave spectroscopy, ozone is a bent molecule, with C 2v symmetry (similar to the water molecule). [30] The O–O distances are 127.2 pm (1.272 Å). The O–O–O angle is 116.78°. [31] The central atom is sp² hybridized with one lone pair. Ozone is a polar molecule with a dipole moment of 0.53 D. [32]
Ozone-oxygen cycle in the ozone layer. The photochemical mechanisms that give rise to the ozone layer were discovered by the British physicist Sydney Chapman in 1930. Ozone in the Earth's stratosphere is created by ultraviolet light striking ordinary oxygen molecules containing two oxygen atoms (O 2), splitting them into individual oxygen atoms (atomic oxygen); the atomic oxygen then combines ...
ozone photodissociation: O 3 + ℎν (240–310 nm) → O 2 + O. The atomic oxygen produced may react with another oxygen molecule to reform ozone via the ozone creation reaction (reaction 2 above). These two reactions thus form the ozone–oxygen cycle, wherein the chemical energy released by ozone creation becomes molecular kinetic energy.
These ozone molecules absorb UVB light, following which ozone splits into a molecule of O 2 and an oxygen atom. The oxygen atom then joins up with an oxygen molecule to regenerate ozone. This is a continuing process that terminates when an oxygen atom recombines with an ozone molecule to make two O 2 molecules. It is worth noting that ozone is ...
The most familiar is molecular oxygen (O 2), present at significant levels in Earth's atmosphere and also known as dioxygen or triplet oxygen. Another is the highly reactive ozone (O 3). Others are: Atomic oxygen (O 1), a free radical. Singlet oxygen (O * 2), one of two metastable states of molecular oxygen. Tetraoxygen (O 4), another ...
Tetraoxygen was first predicted in 1924 by Gilbert N. Lewis, who proposed it as an explanation for the failure of liquid oxygen to obey Curie's law. [1] Though not entirely inaccurate, computer simulations indicate that although there are no stable O 4 molecules in liquid oxygen, O 2 molecules do tend to associate in pairs with antiparallel spins, forming transient O 4 units. [2]
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Chlorine monoxide is a chemical radical with the chemical formula ClO •. It plays an important role in the process of ozone depletion. In the stratosphere, chlorine atoms react with ozone molecules to form chlorine monoxide and oxygen. Cl • + O 3 → ClO • + O 2. This reaction causes the depletion of the ozone layer. [1]