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While "magnesium oxide" normally refers to MgO, the compound magnesium peroxide MgO 2 is also known. According to evolutionary crystal structure prediction, [11] MgO 2 is thermodynamically stable at pressures above 116 GPa (gigapascals), and a semiconducting suboxide Mg 3 O 2 is thermodynamically stable above 500 GPa.
Periclase is a magnesium mineral that occurs naturally in contact metamorphic rocks and is a major component of most basic refractory bricks. It is a cubic form of magnesium oxide (Mg O). In nature it usually forms a solid solution with wüstite (FeO) and is then referred to as ferropericlase or magnesiowüstite. [6]
In both, magnesium oxide is the precursor to magnesium metal. The magnesium oxide is produced as a solid solution with calcium oxide by calcining the mineral dolomite, which is a solid solution of calcium and magnesium carbonates: CaCO 3 ·MgCO 3 → MgO·CaO + 2 CO 2. Reduction occurs at high temperatures with silicon.
The structure of MgO 2 has been calculated as a triangular shape with the O 2 molecule binding side-on to the magnesium. This arrangement is a result of the Mg + donating charge to the oxygen and creating a Mg 2+ O 2 2−. The bond between to O 2 and the magnesium atom has an approximate dissociation energy of 90 kJ mol −1. [1]
The spinels are any of a class of minerals of general formulation AB 2 X 4 which crystallise in the cubic (isometric) crystal system, with the X anions (typically chalcogens, like oxygen and sulfur) arranged in a cubic close-packed lattice and the cations A and B occupying some or all of the octahedral and tetrahedral sites in the lattice.
Calcium oxide (formula: Ca O), commonly known as quicklime or burnt lime, is a widely used chemical compound. It is a white, caustic , alkaline , crystalline solid at room temperature . The broadly used term lime connotes calcium-containing inorganic compounds , in which carbonates , oxides , and hydroxides of calcium, silicon , magnesium ...
Spinel (/ s p ɪ ˈ n ɛ l, ˈ s p ɪ n əl / [7]) is the magnesium/aluminium member of the larger spinel group of minerals. It has the formula MgAl 2 O 4 in the cubic crystal system. Its name comes from the Latin word spinella, a diminutive form of spine, in reference to its pointed crystals. [5]
Magnesium selenide is an inorganic compound with the chemical formula MgSe. It contains magnesium and selenium in a 1:1 ratio. It belongs to the II-VI family of semiconductor compounds.