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Pauling's second rule is that the value of the first pK a for acids of the formula XO m (OH) n depends primarily on the number of oxo groups m, and is approximately independent of the number of hydroxy groups n, and also of the central atom X. Approximate values of pK a are 8 for m = 0, 2 for m = 1, −3 for m = 2 and < −10 for m = 3. [28]
In computational biology, protein pK a calculations are used to estimate the pK a values of amino acids as they exist within proteins.These calculations complement the pK a values reported for amino acids in their free state, and are used frequently within the fields of molecular modeling, structural bioinformatics, and computational biology.
In chemistry and biochemistry, the Henderson–Hasselbalch equation = + ([] []) relates the pH of a chemical solution of a weak acid to the numerical value of the acid dissociation constant, K a, of acid and the ratio of the concentrations, [] [] of the acid and its conjugate base in an equilibrium.
where K ' is the dissociation constant of carbonic acid, which is equal to 800 nmol/L (since K ' = 10 −pKa H 2 CO 3 = 10 −(6.1) ≈ 8.00×10 −7 mol/L = 800 nmol/L). After multiplying the constants (800 × 0.03 = 24) and solving for HCO − 3, the equation is simplified to:
In cell biology, protein kinase A (PKA) is a family of serine-threonine kinase [1] whose activity is dependent on cellular levels of cyclic AMP (cAMP). PKA is also known as cAMP-dependent protein kinase (EC 2.7.11.11). PKA has several functions in the cell, including regulation of glycogen, sugar, and lipid metabolism.
A man accused of murdering a teenager has told a court he heard "screaming" but did not see the killing happen. Jamie Meah, 18, was stabbed to death and a 16-year-old boy was seriously injured ...
The general formula of a phosphoric acid is H n+2−2x P n O 3n+1−x, where n is the number of phosphorus atoms and x is the number of fundamental cycles in the molecule's structure, between 0 and n + 2 / 2 . Pyrophosphate anion. Trimethyl orthophosphate.
Virtually every cell in the body requires iron in order to function well. Iron is involved in key bodily processes, including the transportation of oxygen in the blood. It also plays a central ...