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The PPS (polyphenylene sulfide) polymer is formed by reaction of sodium sulfide with 1,4-dichlorobenzene: n ClC 6 H 4 Cl + n Na 2 S → [C 6 H 4 S] n + 2n NaCl Hill and Edmonds, developers of PPS. The process for commercially producing this material was initially developed by Dr. H. Wayne Hill Jr. and James T. Edmonds at Phillips Petroleum. [7]
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Polyphenyl ethers (PPEs) are obtained by repeated application of the Ullmann Ether Synthesis: reaction of an alkali-metal phenate with a halogenated benzene catalyzed by copper. [ 1 ] PPEs of up to 6 phenyl rings, both oxy and thio ethers, are commercially available.
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Poly(p-phenylene oxide) (PPO), poly(p-phenylene ether) (PPE), poly(oxy-2,6-dimethyl-1,4-phenylene), often referred to simply as polyphenylene oxide, is a high-temperature thermoplastic with the general formula (C 8 H 8 O) n. It is rarely used in its pure form due to difficulties in processing.
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Fragment of the solid-state structure of Na 2 S 5. The S 2− 5 chain consists of the yellow-colored atoms. [3] The alkali metal polysulfides arise by treatment of a solution of the sulfide with elemental sulfur, e.g. sodium sulfide to sodium polysulfide: S 2− + n S → S 2− n+1
Poly(p-phenylene vinylene) (PPV, or polyphenylene vinylene) is a conducting polymer of the rigid-rod polymer family. PPV is the only polymer of this type that can be processed into a highly ordered crystalline thin film.
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