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At 3% fission products by weight, one ton of used fuel will contain about 400 grams of rhodium. The longest lived radioisotope of rhodium is 102m Rh with a half-life of 2.9 years, while the ground state (102 Rh) has a half-life of 207 days. [1] Each kilogram of fission rhodium will contain 6.62 ng of 102 Rh and 3.68 ng of 102m Rh.
Cartoon cross-section showing manto ore deposits (USGS) [1] A polymetallic replacement deposit, also known as carbonate replacement deposit or high-temperature carbonate-hosted Ag-Pb-Zn deposit, [2] is an orebody of metallic minerals formed by the replacement of sedimentary, usually carbonate rock, by metal-bearing solutions in the vicinity of igneous intrusions. [3]
For the ores Cu 2 S and ZnS , balanced equations for the roasting are: 2 Cu 2 S + 3 O 2 → 2 Cu 2 O + 2 SO 2 2 ZnS + 3 O 2 → 2 ZnO + 2 SO 2. The gaseous product of sulfide roasting, sulfur dioxide (SO 2) is often used to produce sulfuric acid. Many sulfide minerals contain other components such as arsenic that are released into the environment.
Iron oxide copper gold (IOCG) deposits are considered to be metasomatic expressions of large crustal-scale alteration events driven by intrusive activity. The deposit type was first recognised by discovery and study of the supergiant Olympic Dam copper-gold-uranium deposit (Olympic Dam mine), and South American examples.
The patio process is a process for extracting silver from ore. Smelting, or refining, is most often necessary because silver is only infrequently found as a native element like some metals nobler than the redox couple 2 H + + 2 e − ⇌ H 2 (gold, mercury, ...). Instead, it is made up of a larger ore body.
Unlike copper, for which the larger hydration energy of Cu 2+ as compared to Cu + is the reason why the former is the more stable in aqueous solution and solids despite lacking the stable filled d-subshell of the latter, with silver this effect is swamped by its larger second ionisation energy.
For sulfide ores, a different process is taken for beneficiation. The ore needs to have the sulfur removed before smelting can begin. Roasting is the primary method of separating, where wood was placed on heaps of ore and set on fire to help with oxidation. [6] [7] 2 Cu 2 S + 3 O 2 → 2 Cu 2 O + 2 SO 2
The black silver sulfide (Ag 2 S) is among the most insoluble salts in aqueous solution, a property that is exploited for separating silver ions from other positive ions. Sodium chloride (NaCl) or common table salt is known to corrode silver-copper alloy, typically seen in silver salt shakers where corrosion appears around the holes in the top.