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Hydrated rhodium trichloride is reduced by carbon monoxide, ethylene, and trifluorophosphine to give rhodium(I) complexes Rh 2 Cl 2 L 4 (L = CO, C 2 H 4, PF 3). When treated with triphenylphosphine , hydrated rhodium trichloride converts to the maroon-colored RhCl(P(C 6 H 5 ) 3 ) 3 , which is known as Wilkinson's catalyst .
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For the ores Cu 2 S and ZnS , balanced equations for the roasting are: 2 Cu 2 S + 3 O 2 → 2 Cu 2 O + 2 SO 2 2 ZnS + 3 O 2 → 2 ZnO + 2 SO 2. The gaseous product of sulfide roasting, sulfur dioxide (SO 2) is often used to produce sulfuric acid. Many sulfide minerals contain other components such as arsenic that are released into the environment.
Cartoon cross-section showing manto ore deposits (USGS) [1] A polymetallic replacement deposit, also known as carbonate replacement deposit or high-temperature carbonate-hosted Ag-Pb-Zn deposit, [2] is an orebody of metallic minerals formed by the replacement of sedimentary, usually carbonate rock, by metal-bearing solutions in the vicinity of igneous intrusions. [3]
For sulfide ores, a different process is taken for beneficiation. The ore needs to have the sulfur removed before smelting can begin. Roasting is the primary method of separating, where wood was placed on heaps of ore and set on fire to help with oxidation. [6] [7] 2 Cu 2 S + 3 O 2 → 2 Cu 2 O + 2 SO 2
The Silver Mask (Romanian: Masca de argint) is a 1985 Romanian action historical film directed by Gheorghe Vitanidis. [1] This is the fourth film in the Margelatu series, [2] after Drumul oaselor (1980), Trandafirul galben (1982), Misterele Bucureștilor (1983), followed by Colierul de turcoaze (1986) and Totul se plătește (1987).
The oxygen in the ore binds to carbon at high temperatures, as the chemical potential energy of the bonds in carbon dioxide (CO 2) is lower than that of the bonds in the ore. Sulfide ores such as those commonly used to obtain copper, zinc or lead, are roasted before smelting in order to convert the sulfides to oxides, which are more readily ...