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More conveniently, the salt can be made by reacting nitric acid with aluminium hydroxide. Aluminium nitrate may also be prepared a metathesis reaction between aluminium sulfate and a nitrate salt with a suitable cation such as barium, strontium, calcium, silver, or lead. e.g. Al 2 (SO 4) 3 + 3 Ba(NO 3) 2 → 2 Al(NO 3) 3 + 3 BaSO 4.
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2 kno 3 + 4 al + s → k 2 s + n 2 + 2 al 2 o 3 The composition is approximately 59% KNO 3 : 31.6% Al : 9.4% S by weight for the reactants of the above stoichiometrically balanced equation. For best results, "German Dark" aluminum should be used, with air float sulfur, and finely ball milled pure potassium nitrate.
A common nitrate test, known as the brown ring test[ 2 ] can be performed by adding iron (II) sulfate to a solution of a nitrate, then slowly adding concentrated sulfuric acid such that the acid forms a layer below the aqueous solution. A brown ring will form at the junction of the two layers, indicating the presence of the nitrate ion. [ 3 ]
Chemically, aluminium is a post-transition metal in the boron group; as is common for the group, aluminium forms compounds primarily in the +3 oxidation state. The aluminium cation Al 3+ is small and highly charged; as such, it has more polarizing power, and bonds formed by aluminium have a more covalent character.
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Alkali metal nitrates are chemical compounds consisting of an alkali metal (lithium, sodium, potassium, rubidium and caesium) and the nitrate ion. Only two are of major commercial value, the sodium and potassium salts. [1] They are white, water-soluble salts with melting points ranging from 255 °C (LiNO. The melting point of the alkali metal ...
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