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Polyvinylcarbazole (PVK) is a temperature-resistant [2] thermoplastic polymer produced by radical polymerization from the monomer N-vinylcarbazole. It is a photoconductive polymer and thus the basis for photorefractive polymers and organic light-emitting diodes .
Upon exposure to γ-irradiation, N-vinylcarbazole undergoes solid-state polymerisation. [ 5 ] It is produced by the vinylation of carbazole with acetylene in the presence of base.
Piezospectroscopy (also known as photoluminescence piezospectroscopy) is an analytical technique that reveals internal stresses in alumina-containing materials, particularly thermal barrier coatings (TBCs).
Living cationic polymerization is a living polymerization technique involving cationic propagating species. [1] [2] It enables the synthesis of very well defined polymers (low molar mass distribution) and of polymers with unusual architecture such as star polymers and block copolymers and living cationic polymerization is therefore as such of commercial and academic interest.
Electrochemiluminescence or electrogenerated chemiluminescence (ECL) is a kind of luminescence produced during electrochemical reactions in solutions. In electrogenerated chemiluminescence, electrochemically generated intermediates undergo a highly exergonic reaction to produce an electronically excited state that then emits light upon relaxation to a lower-level state.
In one modification, both steps are rolled into one by carrying out the reaction in acetic acid. [9] In the third step, this compound is oxidized by red lead to carbazole itself. Another classic is the Bucherer carbazole synthesis, which uses a naphthol and an aryl hydrazine. [10] Bucherer carbazole synthesis
This is the photoluminescence of two very similarly structured polyfluorene derivatives. The one on the left (purple) is a copolymerization of a fluorene derivative, benzene and oxadiazole molecules and the one on the right (light green) has the structure directly below this image.
Poly(p-phenylene vinylene) (PPV, or polyphenylene vinylene) is a conducting polymer of the rigid-rod polymer family. PPV is the only polymer of this type that can be processed into a highly ordered crystalline thin film. PPV and its derivatives are electrically conducting upon doping.