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[a] While processes in isolated systems are never reversible, [3] cyclical processes can be reversible or irreversible. [4] Reversible processes are hypothetical or idealized but central to the second law of thermodynamics. [3] Melting or freezing of ice in water is an example of a realistic process that is nearly reversible.
A process is said to be physically reversible if it results in no increase in physical entropy; it is isentropic. There is a style of circuit design ideally exhibiting this property that is referred to as charge recovery logic , adiabatic circuits , or adiabatic computing (see Adiabatic process ).
First, it states that the microscopic detailed dynamics of particles and fields is time-reversible because the microscopic equations of motion are symmetric with respect to inversion in time ; Second, it relates to the statistical description of the kinetics of macroscopic or mesoscopic systems as an ensemble of elementary processes: collisions ...
Many redox processes observed by CV are quasi-reversible or non-reversible. In such cases the thermodynamic potential E 0 1/2 is often deduced by simulation. The irreversibility is indicated by i pa /i pc ≠ 1. Deviations from unity are attributable to a subsequent chemical reaction that is triggered by the electron transfer.
where a reversible path is chosen from absolute zero to the final state, so that for an isothermal reversible process Δ S = Q r e v T {\displaystyle \Delta S={Q_{rev} \over T}} . In general, for any cyclic process the state points can be connected by reversible paths, so that
The cycle is the same as most other heat cycles in that there are four main processes: compression, heat addition, expansion, and heat removal. However, these processes are not discrete, but rather the transitions overlap. The Stirling cycle is a highly advanced subject that has defied analysis by many experts for over 190 years.
For a particular reversible process in general, the work done reversibly on the system, ,, and the heat transferred reversibly to the system, , are not required to occur respectively adiabatically or adynamically, but they must belong to the same particular process defined by its particular reversible path, , through the space of thermodynamic ...
Kelvin said of Carnot's argument that "nothing in the whole range of Natural Philosophy is more remarkable than the establishment of general laws by such a process of reasoning." [ 4 ] Kelvin and his brother James Thomson confirmed the relation experimentally in 1849–50, and it was historically important as a very early successful application ...