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  2. Yamaguchi esterification - Wikipedia

    en.wikipedia.org/wiki/Yamaguchi_esterification

    The Yamaguchi esterification is the chemical reaction of an aliphatic carboxylic acid and 2,4,6-trichlorobenzoyl chloride (TCBC, Yamaguchi reagent) to form a mixed anhydride which, upon reaction with an alcohol in the presence of stoichiometric amount of DMAP, produces the desired ester. It was first reported by Masaru Yamaguchi et al. in 1979 ...

  3. Ester - Wikipedia

    en.wikipedia.org/wiki/Ester

    An ester of a carboxylic acid.R stands for any group (typically hydrogen or organyl) and R ′ stands for any organyl group.. In chemistry, an ester is a compound derived from an acid (organic or inorganic) in which the hydrogen atom (H) of at least one acidic hydroxyl group (−OH) of that acid is replaced by an organyl group (R ′). [1]

  4. Shiina esterification - Wikipedia

    en.wikipedia.org/wiki/Shiina_Esterification

    The successive addition of carboxylic acids and alcohols into a system containing aromatic carboxylic acid anhydride and catalyst produces corresponding carboxylic esters through the process shown in the following figure. In acidic Shiina esterification, Lewis acid catalysts are used, while nucleophilic catalysts are used for Shiina ...

  5. Dimethyl maleate - Wikipedia

    en.wikipedia.org/wiki/Dimethyl_maleate

    Dimethyl maleate can be synthesized from maleic anhydride and methanol, with sulfuric acid acting as acid catalyst, via a nucleophilic acyl substitution for the monomethyl ester, followed by a Fischer esterification reaction for the dimethyl ester.

  6. α,β-Unsaturated carbonyl compound - Wikipedia

    en.wikipedia.org/wiki/Α,β-Unsaturated_carbonyl...

    The carboxyl group of acrylic acid can react with ammonia to form acrylamide, or with an alcohol to form an acrylate ester. Acrylamide and methyl acrylate are commercially important examples of α,β-unsaturated amides and α,β-unsaturated esters, respectively. They also polymerize readily.

  7. Acetylation - Wikipedia

    en.wikipedia.org/wiki/Acetylation

    Acetic anhydride. This reagent is common in the laboratory; its use cogenerates acetic acid. [7] [10] Acetyl chloride. This reagent is also common in the laboratory, but its use cogenerates hydrogen chloride, which can be undesirable. [8] Ketene. At one time acetic anhydride was prepared by the reaction of ketene with acetic acid: [11]

  8. Alkenylsuccinic anhydrides - Wikipedia

    en.wikipedia.org/wiki/Alkenylsuccinic_anhydrides

    In terms of their mode of action, the anhydride is proposed to react with the hydroxyl groups on the cellulose, forming an ester. The alkenyl side-chain modifies the surface properties of the paper product. [2] The application is similar to that for alkyl ketene dimers. In the United States alkenylsuccinic anhydrides are the preferred paper ...

  9. sec-Butyl acetate - Wikipedia

    en.wikipedia.org/wiki/Sec-Butyl_acetate

    sec-Butyl acetate, or s-butyl acetate, is an ester commonly used as a solvent in lacquers and enamels, where it is used in the production of acyclic polymers, vinyl resins, and nitrocellulose. [3] It is a clear flammable liquid with a sweet smell.

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