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Porosimetry is an analytical technique used to determine various quantifiable aspects of a material's porous structure, such as pore diameter, total pore volume, surface area, and bulk and absolute densities. The technique involves the intrusion of a non-wetting liquid (often mercury) at high pressure into a material through the use of a ...
In capillary flow porometry, in opposition to mercury intrusion porosimetry, the wetting liquid enters spontaneously the pores of the sample ensuring a total wetting of the material, and therefore the contact angle of the wetting liquid with the sample is 0 and the previous formula can be simplified as: P= 4*γ/D.
Powder wettability measurement with the Washburn method. In its most general form the Lucas Washburn equation describes the penetration length of a liquid into a capillary pore or tube with time as = (), where is a simplified diffusion coefficient. [4]
The Kelvin equation is dependent upon thermodynamic principles and does not allude to special properties of materials. It is also used for determination of pore size distribution of a porous medium using adsorption porosimetry. The equation is named in honor of William Thomson, also known as Lord Kelvin.
Micro CT of porous medium: Pores of the porous medium shown as purple color and impermeable porous matrix shown as green-yellow color. Pore structure is a common term employed to characterize the porosity, pore size, pore size distribution, and pore morphology (such as pore shape, surface roughness, and tortuosity of pore channels) of a porous medium.
Water evaporation method (pore volume = (weight of saturated sample − weight of dried sample)/density of water) Mercury intrusion porosimetry (several non-mercury intrusion techniques have been developed due to toxicological concerns, and the fact that mercury tends to form amalgams with several metals and alloys). Gas expansion method. [6]
As core samples are the only evidence of the reservoir's formation rock structure, the Core analysis is the "ground truth" data measured at laboratory to comprehend the key petrophysical features of the in-situ reservoir. In the petroleum industry, rock samples are retrieved from the subsurface and measured by oil or service companies' core ...
BET model of multilayer adsorption, that is, a random distribution of sites covered by one, two, three, etc., adsorbate molecules. The concept of the theory is an extension of the Langmuir theory, which is a theory for monolayer molecular adsorption, to multilayer adsorption with the following hypotheses: