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  2. Elimination reaction - Wikipedia

    en.wikipedia.org/wiki/Elimination_reaction

    Elimination reaction of cyclohexanol to cyclohexene with sulfuric acid and heat [1] An elimination reaction is a type of organic reaction in which two substituents are removed from a molecule in either a one- or two-step mechanism. [2] The one-step mechanism is known as the E2 reaction, and the two-step mechanism is known as the E1 reaction ...

  3. Hammond's postulate - Wikipedia

    en.wikipedia.org/wiki/Hammond's_postulate

    In an E2 mechanism, a base takes a proton near the leaving group, forcing the electrons down to make a double bond, and forcing off the leaving group-all in one concerted step. The rate law depends on the first order concentration of two reactants, making it a 2nd order (bimolecular) elimination reaction.

  4. Collision theory - Wikipedia

    en.wikipedia.org/wiki/Collision_theory

    The rate for a bimolecular gas-phase reaction, A + B → product, predicted by collision theory is [6] = = ⁡ ()where: k is the rate constant in units of (number of molecules) −1 ⋅s −1 ⋅m 3.

  5. List of equations in nuclear and particle physics - Wikipedia

    en.wikipedia.org/wiki/List_of_equations_in...

    The following apply for the nuclear reaction: a + b ↔ R → c in the centre of mass frame , where a and b are the initial species about to collide, c is the final species, and R is the resonant state .

  6. Solvent effects - Wikipedia

    en.wikipedia.org/wiki/Solvent_effects

    The rate equation for S N 2 reactions are bimolecular being first order in Nucleophile and first order in Reagent. The determining factor when both S N 2 and S N 1 reaction mechanisms are viable is the strength of the Nucleophile. Nuclephilicity and basicity are linked and the more nucleophilic a molecule becomes the greater said nucleophile's ...

  7. Binding energy - Wikipedia

    en.wikipedia.org/wiki/Binding_energy

    Mass change = (unbound system calculated mass) − (measured mass of system) e.g. (sum of masses of protons and neutrons) − (measured mass of nucleus) After a nuclear reaction occurs that results in an excited nucleus, the energy that must be radiated or otherwise removed as binding energy in order to decay to the unexcited state may be in ...

  8. Mayo–Lewis equation - Wikipedia

    en.wikipedia.org/wiki/Mayo–Lewis_equation

    The reactivity ratio for each propagating chain end is defined as the ratio of the rate constant for addition of a monomer of the species already at the chain end to the rate constant for addition of the other monomer.

  9. Reactivity (chemistry) - Wikipedia

    en.wikipedia.org/wiki/Reactivity_(chemistry)

    In chemistry, reactivity is the impulse for which a chemical substance undergoes a chemical reaction, either by itself or with other materials, with an overall release of energy. Reactivity refers to: the chemical reactions of a single substance, the chemical reactions of two or more substances that interact with each other,