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In aqueous solution, ammonia deprotonates a small fraction of the water to give ammonium and hydroxide according to the following equilibrium: . NH 3 + H 2 O ⇌ NH + 4 + OH −.. In a 1 M ammonia solution, about 0.42% of the ammonia is converted to ammonium, equivalent to pH = 11.63 because [NH +
Otherwise temperature is equilibrium of vapor over liquid. log 10 of anydrous ammonia vapor pressure. Uses formula shown below. Vapor-pressure formula for ammonia: [4]
If the pH is high (the concentration of hydrogen ions is low and hydroxide ions is high), the equilibrium shifts to the left: the hydroxide ion abstracts a proton from the ammonium ion, generating ammonia. Formation of ammonium compounds can also occur in the vapor phase; for example, when ammonia vapor comes in contact with hydrogen chloride ...
The tables below provides information on the variation of solubility of different substances (mostly inorganic compounds) in water with temperature, at one atmosphere pressure. Units of solubility are given in grams of substance per 100 millilitres of water (g/100 ml), unless shown otherwise.
Ammonia is commonly used in the illegal manufacture of methamphetamine through a Birch reduction. [123] The Birch method of making methamphetamine is dangerous because the alkali metal and liquid ammonia are both extremely reactive, and the temperature of liquid ammonia makes it susceptible to explosive boiling when reactants are added. [124]
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
Ammonium acetate, also known as spirit of Mindererus in aqueous solution, is a chemical compound with the formula NH 4 CH 3 CO 2. It is a white, hygroscopic solid and can be derived from the reaction of ammonia and acetic acid .
Solid monoammonium phosphate can be considered stable in practice for temperatures up to 200 °C, when it decomposes into gaseous ammonia NH 3 and molten phosphoric acid H 3 PO 4. [9] At 125 °C the partial pressure of ammonia is 0.05 mm Hg. [10] A solution of stoichometric monoammonium phosphate is acidic (pH 4.7 at 0.1% concentration, 4.2 at ...