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In organic chemistry, an electrocyclic reaction can either be classified as conrotatory or disrotatory based on the rotation at each end of the molecule. In conrotatory mode, both atomic orbitals of the end groups turn in the same direction (such as both atomic orbitals rotating clockwise or counter-clockwise). In disrotatory mode, the atomic ...
Absolute configuration uses a set of rules to describe the relative positions of each bond around the chiral center atom. The most common labeling method uses the descriptors R or S and is based on the Cahn–Ingold–Prelog priority rules. R and S refer to rectus and sinister, Latin for right and left, respectively.
Optical activity is reciprocal, i.e. it is the same for opposite directions of wave propagation through an optically active medium, for example, clockwise polarization rotation from the point of view of an observer. In case of optically active isotropic media, the rotation is the same for any direction of wave propagation.
Two-dimensional rotation can occur in two possible directions or senses of rotation.Clockwise motion (abbreviated CW) proceeds in the same direction as a clock's hands relative to the observer: from the top to the right, then down and then to the left, and back up to the top.
A sphere rotating (spinning) about an axis. Rotation or rotational motion is the circular movement of an object around a central line, known as an axis of rotation.A plane figure can rotate in either a clockwise or counterclockwise sense around a perpendicular axis intersecting anywhere inside or outside the figure at a center of rotation.
In chemistry, specific rotation ([α]) is a property of a chiral chemical compound. [ 1 ] : 244 It is defined as the change in orientation of monochromatic plane-polarized light , per unit distance–concentration product, as the light passes through a sample of a compound in solution.
The angle θ and axis unit vector e define a rotation, concisely represented by the rotation vector θe.. In mathematics, the axis–angle representation parameterizes a rotation in a three-dimensional Euclidean space by two quantities: a unit vector e indicating the direction of an axis of rotation, and an angle of rotation θ describing the magnitude and sense (e.g., clockwise) of the ...
The rotation of light is measured using a polarimeter and is expressed as the optical rotation. Enantiomers can be separated by chiral resolution . This often involves forming crystals of a salt composed of one of the enantiomers and an acid or base from the so-called chiral pool of naturally occurring chiral compounds, such as malic acid or ...