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A superabsorbent polymer (SAP) (also called slush powder) is a water-absorbing hydrophilic homopolymers or copolymers [1] that can absorb and retain extremely large amounts of a liquid relative to its own mass. [2] Water-absorbing polymers, which are classified as hydrogels when mixed, [3] absorb aqueous solutions through hydrogen bonding with ...
In polymer chemistry, suspension polymerization is a heterogeneous radical polymerization process that uses mechanical agitation to mix a monomer or mixture of monomers in a liquid phase, such as water, while the monomers polymerize, forming spheres of polymer. [2] The monomer droplets (size of the order 10-1000 μm) are suspended in the liquid ...
Another application of polymer solutions includes the manufacture of fibers by wet or dry spinning or plastic films. Disadvantages of solution polymerization are decrease of monomer and initiator concentration leading to reduction of reaction rate, lower volume utilization of reactor, additional cost of the process related to solvent recycling ...
A small amount of superabsorbent polymer material is taken (0.1g) and it is placed in the beaker. 100 ml of deionized water is poured into the beaker. After 20 min the swollen polymer was separated by using [filter paper] By weighing the polymer, one can find the swollen capacity of the SAP material. [3]
Bulk polymerization or mass polymerization is carried out by adding a soluble radical initiator to pure monomer in liquid state. The initiator should dissolve in the monomer. The reaction is initiated by heating or exposing to radiation. As the reaction proceeds the mixture becomes more viscous.
The liquid molecules are more attracted to other liquid molecules as compared to the polymer surface. Because the polymer surfaces are solid surfaces, surface tension cannot be measured in a traditional way such as using a Wilhelmy plate. Instead, contact angles can be used to indirectly estimate the surface tension of polymer surfaces. [3]
In a liquid-liquid interface with monomer dissolved in one phase, polymerization occurs on only one side of the interface, whereas in liquid-liquid interfaces with monomer dissolved in both phases, polymerization occurs on both sides. [2] An interfacial polymerization reaction may proceed either stirred or unstirred.
The phase behavior of polymer solutions is an important property involved in the development and design of most polymer-related processes. Partially miscible polymer solutions often exhibit two solubility boundaries, the upper critical solution temperature (UCST) and the LCST, both of which depend on the molar mass and the pressure. At ...