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The concentrated area with high stress works as anode and diluted area works as cathode. At anode, sodium hydroxide attacks the surrounding material and then dissolves the iron of the boiler as sodium ferrate forming rust. This causes embrittlement of boiler parts like rivets, bends and joints, which are under stress.
erosion of a boiler's plates from the internal water space, particularly where there is a step inside the shell. This was a problem for early boilers made from lapped plates rather than butted plates, and gave rise to many boiler explosions. In later years it was a problem for the non-circular water drums of Yarrow boilers. Handhole
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