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Watt's indicator diagram. The PV diagram, then called an indicator diagram, was developed in 1796 by James Watt and his employee John Southern. [2] Volume was traced by a plate moving with the piston, while pressure was traced by a pressure gauge whose indicator moved at right angles to the piston.
Isotherms of an ideal gas for different temperatures. The curved lines are rectangular hyperbolae of the form y = a/x. They represent the relationship between pressure (on the vertical axis) and volume (on the horizontal axis) for an ideal gas at different temperatures: lines that are farther away from the origin (that is, lines that are nearer to the top right-hand corner of the diagram ...
The laws describing the behaviour of gases under fixed pressure, volume, amount of gas, and absolute temperature conditions are called gas laws.The basic gas laws were discovered by the end of the 18th century when scientists found out that relationships between pressure, volume and temperature of a sample of gas could be obtained which would hold to approximation for all gases.
For a fixed mass of an ideal gas kept at a fixed temperature, pressure and volume are inversely proportional. [2] Boyle's law is a gas law, stating that the pressure and volume of a gas have an inverse relationship. If volume increases, then pressure decreases and vice versa, when the temperature is held constant.
All four diagrams are derived from the physical P–alpha diagram which combines pressure (P) and specific volume (alpha) as its basic coordinates. The P–alpha diagram shows a strong deformation of the grid for atmospheric conditions and is therefore not useful in atmospheric sciences. The three diagrams are constructed from the P–alpha ...
An indicator diagram is a chart used to measure the thermal, or cylinder, performance of reciprocating steam and internal combustion engines and compressors. [1] An indicator chart records the pressure in the cylinder versus the volume swept by the piston, throughout the two or four strokes of the piston which constitute the engine, or ...
Pressure, temperature, enthalpy, entropy, specific volume, and internal energy are the most common. Pressure–volume diagram showing state (p,V) If at least two thermodynamic properties are known, the state of the working fluid can be defined. This is usually done on a property diagram which is simply a plot of one property versus another.
For example, if the volume is halved, the pressure is doubled; and if the volume is doubled, the pressure is halved. Given the inverse relationship between pressure and volume, the product of pressure (P) and volume (V) is a constant (k) for a given mass of confined gas as long as the temperature is constant. Stated as a formula, thus is: