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Depending upon substitution, the UV absorption spectrum is changed to match the application. Concentrations normally range from 0.05% to 2%, with some applications up to 5%. Frequently, glass can be a better alternative to polymers when it comes to UV degradation. Most of the commonly used glass types are highly resistant to UV radiation ...
Polypropylene (PP), also known as polypropene, is a thermoplastic polymer used in a wide variety of applications. It is produced via chain-growth polymerization from the monomer propylene . Polypropylene belongs to the group of polyolefins and is partially crystalline and non-polar .
UV damaged polypropylene rope (left) and new rope (right) UV degradation is one form of polymer degradation that affects plastics exposed to sunlight. The problem appears as discoloration or fading, cracking, loss of strength or disintegration. The effects of attack increase with exposure time and sunlight intensity.
Rope may be constructed of any long, stringy, fibrous material (e.g., rattan, a natural material), but generally is constructed of certain natural or synthetic fibres. [1] [2] [3] Synthetic fibre ropes are significantly stronger than their natural fibre counterparts, they have a higher tensile strength, they are more resistant to rotting than ropes created from natural fibres, and they can be ...
Pentaerythritol tetrakis(3,5-di-tert-butyl-4-hydroxyhydrocinnamate): A primary antioxidant consisting of sterically hindered phenols with para-propionate groups. Primary antioxidants (also known as chain-breaking antioxidants) act as radical scavengers and remove peroxy radicals (ROO•), as well as to a lesser extent alkoxy radicals (RO•), hydroxyl radicals (HO•) and alkyl radicals (R•).
Discolouration of the rope may also occur, thus giving an early warning of the problem. Polymers which possess UV-absorbing groups such as aromatic rings may also be sensitive to UV degradation. Aramid fibres like Kevlar , for example, are highly UV-sensitive and must be protected from the deleterious effects of sunlight.
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