Search results
Results from the WOW.Com Content Network
The reaction has been the subject of several literature reviews. [1] [2] [3] The Nef reaction: 1. Salt of a nitroalkane 3. Ketone 4. Nitrous oxide. The reaction was reported in 1894 by the chemist John Ulric Nef, [4] who treated the sodium salt of nitroethane with sulfuric acid resulting in an 85–89% yield of nitrous oxide and at least 70% ...
Nitroethane is an organic compound having the chemical formula C 2 H 5 NO 2. Similar in many regards to nitromethane , nitroethane is an oily liquid at standard temperature and pressure. Pure nitroethane is colorless and has a fruity odor.
Other agents are water-soluble and are used for the aqueous salt solution. As mentioned above, water-soluble gums and gel modifiers (like guar) can be used for the gelling of aqueous solutions. When the salt solution and nitroparaffin are gelled, the entire mixture is combined and mixed together until the desired consistency is achieved.
In the so-called Ter Meer reaction (1876) named after Edmund ter Meer, [14] the reactant is a 1,1-halonitroalkane: The reaction mechanism is proposed in which in the first slow step a proton is abstracted from nitroalkane 1 to a carbanion 2 followed by protonation to an aci-nitro 3 and finally nucleophilic displacement of chlorine based on an ...
Gas phase ion chemistry is a field of science encompassed within both chemistry and physics. It is the science that studies ions and molecules in the gas phase, most often enabled by some form of mass spectrometry. By far the most important applications for this science is in studying the thermodynamics and kinetics of reactions.
Lomonosov also insisted that movement of particles is necessary for the processes of dissolution, extraction and diffusion, providing as examples the dissolution and diffusion of salts by the action of water particles on the of the “molecules of salt”, the dissolution of metals in mercury, and the extraction of plant pigments by alcohol. [14]
Nitromethane reacts with solutions of sodium hydroxide or methoxide in alcohol to produce an insoluble salt of nitromethane. This substance is a sensitive explosive which reverts to nitromethane under acidic conditions and decomposes in water to form another explosive compound, sodium methazonate, which has a reddish-brown color:
Incomplete reaction at higher temperature further curtails the effect of a larger heat of combustion. [ citation needed ] Because most combustion processes that happen naturally occur in the open air, there is nothing that confines the gas to a particular volume like the cylinder in an engine.