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The real and imaginary parts of permittivity are shown, and various processes are depicted: ionic and dipolar relaxation, and atomic and electronic resonances at higher energies. [ 1 ] Dielectric spectroscopy (which falls in a subcategory of the impedance spectroscopy ) measures the dielectric properties of a medium as a function of frequency .
In general, permittivity is not a constant, as it can vary with the position in the medium, the frequency of the field applied, humidity, temperature, and other parameters. In a nonlinear medium, the permittivity can depend on the strength of the electric field. Permittivity as a function of frequency can take on real or complex values.
The relative permittivity of a medium is related to its electric susceptibility, χ e, as ε r (ω) = 1 + χ e. In anisotropic media (such as non cubic crystals) the relative permittivity is a second rank tensor. The relative permittivity of a material for a frequency of zero is known as its static relative permittivity.
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is the speed of light (i.e. phase velocity) in a medium with permeability μ, and permittivity ε, and ∇ 2 is the Laplace operator. In a vacuum, v ph = c 0 = 299 792 458 m/s, a fundamental physical constant. [1] The electromagnetic wave equation derives from Maxwell's equations.
For gases (e.g. nitrogen, sulfur hexafluoride) it normally decreases with increased humidity as ions in water can provide conductive channels. For gases it increases with pressure according to Paschen's law; For air, dielectric strength increases slightly as the absolute humidity increases but decreases with an increase in relative humidity [2]
All quantities are in Gaussian units except energy and temperature which are in electronvolts.For the sake of simplicity, a single ionic species is assumed. The ion mass is expressed in units of the proton mass, = / and the ion charge in units of the elementary charge, = / (in the case of a fully ionized atom, equals to the respective atomic number).
The Born equation can be used for estimating the electrostatic component of Gibbs free energy of solvation of an ion. It is an electrostatic model that treats the solvent as a continuous dielectric medium (it is thus one member of a class of methods known as continuum solvation methods). It was derived by Max Born. [1] [2]