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Efficient and economical water splitting would be a technological breakthrough that could underpin a hydrogen economy. A version of water splitting occurs in photosynthesis, but hydrogen is not produced. The reverse of water splitting is the basis of the hydrogen fuel cell. Water splitting using solar radiation has not been commercialized.
The oxygen-evolving complex (OEC), also known as the water-splitting complex, is a water-oxidizing enzyme involved in the photo-oxidation of water during the light reactions of photosynthesis. [3] OEC is surrounded by 4 core proteins of photosystem II at the membrane-lumen interface.
The process of water-splitting is a highly endothermic process (ΔH > 0). Water splitting occurs naturally in photosynthesis when the energy of four photons is absorbed and converted into chemical energy through a complex biochemical pathway (Dolai's or Kok's S-state diagrams). [3] O–H bond homolysis in water requires energy of 6.5 - 6.9 eV ...
Heterogeneous photocatalysis is a discipline which includes a large variety of reactions: mild or total oxidations, dehydrogenation, hydrogen transfer, 18 O 2 – 16 O 2 and deuterium-alkane isotopic exchange, metal deposition, water detoxification, and gaseous pollutant removal.
This occurs by oxidation of water in the case of oxygenic photosynthesis. The electron-deficient reaction center of photosystem II (P680*) is the strongest biological oxidizing agent yet discovered, which allows it to break apart molecules as stable as water. [4] The water-splitting reaction is catalyzed by the oxygen-evolving complex of ...
Of the two half reactions, the oxidation step is the most demanding because it requires the coupling of 4 electron and proton transfers and the formation of an oxygen-oxygen bond. This process occurs naturally in plants photosystem II to provide protons and electrons for the photosynthesis process and release oxygen to the atmosphere, [ 1 ] as ...
The semiconductor crucial to this process, absorbs sunlight, initiating electron excitation and subsequent water molecule splitting into hydrogen and oxygen. Photoanode Reaction (Oxygen Evolution): H2O → 2H++1 2O2+ 2e−. Photocathode Reaction (Hydrogen Evolution): 2H++ 2e− → H2. 41598 2017 11971
Photosystem II (or water-plastoquinone oxidoreductase) is the first protein complex in the energy-dependent reactions of oxygenic photosynthesis. It is located in the thylakoid membrane of plants , algae , and cyanobacteria .