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  2. 68–95–99.7 rule - Wikipedia

    en.wikipedia.org/wiki/68–95–99.7_rule

    In statistics, the 68–95–99.7 rule, also known as the empirical rule, and sometimes abbreviated 3sr or 3 σ, is a shorthand used to remember the percentage of values that lie within an interval estimate in a normal distribution: approximately 68%, 95%, and 99.7% of the values lie within one, two, and three standard deviations of the mean ...

  3. Empirical formula - Wikipedia

    en.wikipedia.org/wiki/Empirical_formula

    In chemistry, the empirical formula of a chemical compound is the simplest whole number ratio of atoms present in a compound. [1] A simple example of this concept is that the empirical formula of sulfur monoxide, or SO, is simply SO, as is the empirical formula of disulfur dioxide, S 2 O 2.

  4. Arrhenius equation - Wikipedia

    en.wikipedia.org/wiki/Arrhenius_equation

    In physical chemistry, the Arrhenius equation is a formula for the temperature dependence of reaction rates.The equation was proposed by Svante Arrhenius in 1889, based on the work of Dutch chemist Jacobus Henricus van 't Hoff who had noted in 1884 that the Van 't Hoff equation for the temperature dependence of equilibrium constants suggests such a formula for the rates of both forward and ...

  5. Law of large numbers - Wikipedia

    en.wikipedia.org/wiki/Law_of_large_numbers

    The Italian mathematician Gerolamo Cardano (1501–1576) stated without proof that the accuracies of empirical statistics tend to improve with the number of trials. [9] [3] This was then formalized as a law of large numbers. A special form of the LLN (for a binary random variable) was first proved by Jacob Bernoulli.

  6. Standard deviation - Wikipedia

    en.wikipedia.org/wiki/Standard_deviation

    This formula is valid only if the eight values with which we began form the complete population. ... This is known as the 68–95–99.7 rule, or the empirical rule.

  7. Empirical distribution function - Wikipedia

    en.wikipedia.org/wiki/Empirical_distribution...

    In statistics, an empirical distribution function (a.k.a. an empirical cumulative distribution function, eCDF) is the distribution function associated with the empirical measure of a sample. [1] This cumulative distribution function is a step function that jumps up by 1/n at each of the n data points. Its value at any specified value of the ...

  8. Rydberg–Ritz combination principle - Wikipedia

    en.wikipedia.org/wiki/Rydberg–Ritz_combination...

    The Rydberg–Ritz combination principle is an empirical rule proposed by Walther Ritz in 1908 to describe the relationship of the spectral lines for all atoms, as a generalization of an earlier rule by Johannes Rydberg for the hydrogen atom and the alkali metals.

  9. Power law - Wikipedia

    en.wikipedia.org/wiki/Power_law

    To the right is the long tail, and to the left are the few that dominate (also known as the 80–20 rule). In statistics , a power law is a functional relationship between two quantities, where a relative change in one quantity results in a relative change in the other quantity proportional to the change raised to a constant exponent : one ...