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Hansen solubility parameters were developed by Charles M. Hansen in his Ph.D thesis in 1967 [1] [2] as a way of predicting if one material will dissolve in another and form a solution. [3] They are based on the idea that like dissolves like where one molecule is defined as being 'like' another if it bonds to itself in a similar way.
In addition to over 130 published papers and 8 patents (h-index 25), he authored Hansen Solubility Parameters – A User's Handbook in 1999 followed by an expanded 2nd Edition in 2007. [6] With Abbott and Yamamoto he authored the package of software, eBook, and datasets called Hansen Solubility Parameters in Practice, in 2008 which is currently ...
The solubility of a specific solute in a specific solvent is generally expressed as the concentration of a saturated solution of the two. [1] Any of the several ways of expressing concentration of solutions can be used, such as the mass, volume, or amount in moles of the solute for a specific mass, volume, or mole amount of the solvent or of the solution.
Complete solubility occurs when the solvent and solute have the same valency. [2] A metal is more likely to dissolve a metal of higher valency, than vice versa. [1] [3] [4] The solute and solvent should have similar electronegativity.
3 The constant "4" 4 Interaction Parameter, R 0. 1 comment. 5 Inappropriate Original Research Tag on Page. 1 comment. Toggle the table of contents. Talk: Hansen ...
It is also relatively acidic, with a pKa of 9.3, comparable to that for phenol. [1] It is classified as a hard Lewis acid and its acceptor properties are discussed in the ECW model. [3] [4] Hexafluoro-propan-2-ol is a speciality solvent for organic synthesis, particularly for reactions involving oxidations and strong electrophiles.
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
[1] [2] From a historical point of view MOSCED can be regarded as an improved modification of the Hansen method and the Hildebrand solubility model by adding higher interaction term such as polarity, induction and separation of hydrogen bonding terms.