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  2. Center of pressure (fluid mechanics) - Wikipedia

    en.wikipedia.org/wiki/Center_of_pressure_(fluid...

    Center of pressure is used in sailboat design to represent the position on a sail where the aerodynamic force is concentrated.. The relationship of the aerodynamic center of pressure on the sails to the hydrodynamic center of pressure (referred to as the center of lateral resistance) on the hull determines the behavior of the boat in the wind.

  3. Thermodynamic activity - Wikipedia

    en.wikipedia.org/wiki/Thermodynamic_activity

    The relative activity of a species i, denoted a i, is defined [4] [5] as: = where μ i is the (molar) chemical potential of the species i under the conditions of interest, μ o i is the (molar) chemical potential of that species under some defined set of standard conditions, R is the gas constant, T is the thermodynamic temperature and e is the exponential constant.

  4. Raoult's law - Wikipedia

    en.wikipedia.org/wiki/Raoult's_law

    Raoult's law (/ ˈ r ɑː uː l z / law) is a relation of physical chemistry, with implications in thermodynamics.Proposed by French chemist François-Marie Raoult in 1887, [1] [2] it states that the partial pressure of each component of an ideal mixture of liquids is equal to the vapor pressure of the pure component (liquid or solid) multiplied by its mole fraction in the mixture.

  5. Solid solution - Wikipedia

    en.wikipedia.org/wiki/Solid_solution

    The propensity for any two substances to form a solid solution is a complicated matter involving the chemical, crystallographic, and quantum properties of the substances in question. Substitutional solid solutions, in accordance with the Hume-Rothery rules, may form if the solute and solvent have: Similar atomic radii (15% or less difference)

  6. Depletion force - Wikipedia

    en.wikipedia.org/wiki/Depletion_force

    The difference in concentration of macromolecules in the solution between the plates and the bulk solution causes a force equal to the osmotic pressure to act on the plates. In a very dilute and monodisperse solution the force is defined by = (⁡)

  7. Atmospheric-pressure chemical ionization - Wikipedia

    en.wikipedia.org/wiki/Atmospheric-pressure...

    Ionization in the gas phase by APCI follows the sequences: sample in solution, sample vapor, and sample ions. The effluent from the HPLC is evaporated completely. The mixture of solvent and sample vapor is then ionized by ion-molecule reaction. [9] The ionization can either be carried out in positive or negative ionization mode.

  8. Critical point (thermodynamics) - Wikipedia

    en.wikipedia.org/wiki/Critical_point...

    The commonly known phases solid, liquid and vapor are separated by phase boundaries, i.e. pressure–temperature combinations where two phases can coexist. At the triple point, all three phases can coexist. However, the liquid–vapor boundary terminates in an endpoint at some critical temperature T c and critical pressure p c. This is the ...

  9. Ideal solution - Wikipedia

    en.wikipedia.org/wiki/Ideal_solution

    The simplest definition is that an ideal solution is a solution for which each component obeys Raoult's law = for all compositions. Here p i {\displaystyle p_{i}} is the vapor pressure of component i {\displaystyle i} above the solution, x i {\displaystyle x_{i}} is its mole fraction and p i ∗ {\displaystyle p_{i}^{*}} is the vapor pressure ...