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The exact formulation is as follows. Consider two systems, 1 and 2, in thermal contact, with respective energies E 1 and E 2. We assume E 1 + E 2 = some constant E. The number of microstates of each system will be denoted by Ω 1 and Ω 2. Under our assumptions Ω i depends only on E i.
Quantities, Units and Symbols in Physical Chemistry, also known as the Green Book, is a compilation of terms and symbols widely used in the field of physical chemistry. It also includes a table of physical constants , tables listing the properties of elementary particles , chemical elements , and nuclides , and information about conversion ...
kT (also written as k B T) is the product of the Boltzmann constant, k (or k B), and the temperature, T.This product is used in physics as a scale factor for energy values in molecular-scale systems (sometimes it is used as a unit of energy), as the rates and frequencies of many processes and phenomena depend not on their energy alone, but on the ratio of that energy and kT, that is, on E ...
"The kelvin, symbol K, is the SI unit of thermodynamic temperature. It is defined by taking the fixed numerical value of the Boltzmann constant k to be 1.380 649 × 10 −23 when expressed in the unit J K −1, which is equal to kg m 2 s −2 K −1, where the kilogram, metre and second are defined in terms of h, c and ∆ν Cs." [1]
Cartesian y-axis basis unit vector unitless kinetic energy: joule (J) wave vector: radian per meter (m −1) Boltzmann constant: joule per kelvin (J/K) wavenumber: radian per meter (m −1) stiffness: newton per meter (N⋅m −1) ^ Cartesian z-axis basis unit vector
In solution chemistry and biochemistry, the Gibbs free energy decrease (∂G/∂ξ, in molar units, denoted cryptically by ΔG) is commonly used as a surrogate for (−T times) the global entropy produced by spontaneous chemical reactions in situations where no work is being done; or at least no "useful" work; i.e., other than perhaps ± P dV.
Thermal physics, generally speaking, is the study of the statistical nature of physical systems from an energetic perspective. Starting with the basics of heat and temperature, thermal physics analyzes the first law of thermodynamics and second law of thermodynamics from the statistical perspective, in terms of the number of microstates corresponding to a given macrostate.
Also acid ionization constant or acidity constant. A quantitative measure of the strength of an acid in solution expressed as an equilibrium constant for a chemical dissociation reaction in the context of acid-base reactions. It is often given as its base-10 cologarithm, p K a. acid–base extraction A chemical reaction in which chemical species are separated from other acids and bases. acid ...