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The term molality is formed in analogy to molarity which is the molar concentration of a solution. The earliest known use of the intensive property molality and of its adjectival unit, the now-deprecated molal, appears to have been published by G. N. Lewis and M. Randall in the 1923 publication of Thermodynamics and the Free Energies of Chemical Substances. [3]
Molar concentration (also called molarity, amount concentration or substance concentration) is a measure of the concentration of a chemical species, in particular, of a solute in a solution, in terms of amount of substance per unit volume of solution. In chemistry, the most commonly used unit for molarity is the number of moles per liter ...
The molality of a solution does not change with , since it refers to the mass of the solvent. In contrast, the concentration does change with , since the density of a solution and thus its volume are temperature-dependent. Defining the aqueous-phase composition via molality has the advantage that any temperature dependence of the Henry's law ...
Molar volume. In chemistry and related fields, the molar volume, symbol Vm, [1] or of a substance is the ratio of the volume (V) occupied by a substance to the amount of substance (n), usually at a given temperature and pressure. It is also equal to the molar mass (M) divided by the mass density (ρ): The molar volume has the SI unit of cubic ...
Apparent molar property. In thermodynamics, an apparent molar property of a solution component in a mixture or solution is a quantity defined with the purpose of isolating the contribution of each component to the non-ideality of the mixture. It shows the change in the corresponding solution property (for example, volume) per mole of that ...
Osmotic concentration. Osmotic concentration, formerly known as osmolarity, [1] is the measure of solute concentration, defined as the number of osmoles (Osm) of solute per litre (L) of solution (osmol/L or Osm/L). The osmolarity of a solution is usually expressed as Osm/L (pronounced "osmolar"), in the same way that the molarity of a solution ...
Mole fraction is numerically identical to the number fraction, which is defined as the number of particles (molecules) of a constituent Ni divided by the total number of all molecules Ntot. Whereas mole fraction is a ratio of amounts to amounts (in units of moles per moles), molar concentration is a quotient of amount to volume (in units of ...
In chemistry, the mass concentration ρi (or γi) is defined as the mass of a constituent mi divided by the volume of the mixture V. [1] For a pure chemical the mass concentration equals its density (mass divided by volume); thus the mass concentration of a component in a mixture can be called the density of a component in a mixture.