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Optical rotation, also known as polarization rotation or circular birefringence, is the rotation of the orientation of the plane of polarization about the optical axis of linearly polarized light as it travels through certain materials. Circular birefringence and circular dichroism are the manifestations of optical activity.
Definition. The CRC Handbook of Chemistry and Physics defines specific rotation as: For an optically active substance, defined by [α] θλ = α/γl, where α is the angle through which plane polarized light is rotated by a solution of mass concentration γ and path length l. Here θ is the Celsius temperature and λ the wavelength of the light ...
In the physical sciences, the wavenumber (or wave number), also known as repetency, [1] is the spatial frequency of a wave, measured in cycles per unit distance (ordinary wavenumber) or radians per unit distance (angular wavenumber). [2][3][4] It is analogous to temporal frequency, which is defined as the number of wave cycles per unit time ...
The fine structure energy corrections can be obtained by using perturbation theory.To perform this calculation one must add three corrective terms to the Hamiltonian: the leading order relativistic correction to the kinetic energy, the correction due to the spin–orbit coupling, and the Darwin term coming from the quantum fluctuating motion or zitterbewegung of the electron.
Formally, the wavelength version of Wien's displacement law states that the spectral radiance of black-body radiation per unit wavelength, peaks at the wavelength given by: where T is the absolute temperature and b is a constant of proportionality called Wien's displacement constant, equal to 2.897 771 955... × 10−3 m⋅K, [1][2] or b ≈ ...
Refraction of a light ray. In optics, the refractive index (or refraction index) of an optical medium is the ratio of the apparent speed of light in the medium to the speed in air or vacuum. The refractive index determines how much the path of light is bent, or refracted, when entering a material. This is described by Snell's law of refraction ...
t. e. Matter waves are a central part of the theory of quantum mechanics, being half of wave–particle duality. At all scales where measurements have been practical, matter exhibits wave -like behavior. For example, a beam of electrons can be diffracted just like a beam of light or a water wave. The concept that matter behaves like a wave was ...
In physics and mathematics, wavelength or spatial period of a wave or periodic function is the distance over which the wave's shape repeats. [1][2] In other words, it is the distance between consecutive corresponding points of the same phase on the wave, such as two adjacent crests, troughs, or zero crossings.